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pychu [463]
3 years ago
5

For the gas phase decomposition of 1-bromopropane, CH3CH2CH2BrCH3CH=CH2 + HBr the rate constant at 622 K is 6.43×10-4 /s and the

rate constant at 666 K is 8.28×10-3 /s. The activation energy for the gas phase decomposition of 1-bromopropane is
Chemistry
1 answer:
ladessa [460]3 years ago
4 0

<span>Answer is: activation energy of this reaction is 212,01975 kJ/mol.
Arrhenius equation: ln(k</span>₁/k₂) = Ea/R (1/T₂ - 1/T₁<span>).
k</span>₁<span> = 0,000643 1/s.
k</span>₂ = 0,00828 1/s.

T₁ = 622 K.

T₂ = 666 K.

R = 8,3145 J/Kmol.

1/T₁<span> = 1/622 K = 0,0016 1/K.
1/T</span>₂<span> = 1/666 K = 0,0015 1/K.
ln(0,000643/0,00828) = Ea/8,3145 J/Kmol · (-0,0001 1/K).
-2,55 = Ea/8,3145 J/Kmol · (-0,0001 1/K).
Ea = 212019,75 J/mol = 212,01975 kJ/mol.</span>

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<u>Answer:</u> The concentration of NH_3 required will be 0.285 M.

<u>Explanation:</u>

To calculate the molarity of NiC_2O_4, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}

Moles of NiC_2O_4 = 0.016 moles

Volume of solution = 1 L

Putting values in above equation, we get:

\text{Molarity of }NiC_2O_4=\frac{0.016mol}{1L}=0.016M

For the given chemical equations:

NiC_2O_4(s)\rightleftharpoons Ni^{2+}(aq.)+C_2O_4^{2-}(aq.);K_{sp}=4.0\times 10^{-10}

Ni^{2+}(aq.)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K_f=1.2\times 10^9

Net equation: NiC_2O_4(s)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K=?

To calculate the equilibrium constant, K for above equation, we get:

K=K_{sp}\times K_f\\K=(4.0\times 10^{-10})\times (1.2\times 10^9)=0.48

The expression for equilibrium constant of above equation is:

K=\frac{[C_2O_4^{2-}][[Ni(NH_3)_6]^{2+}]}{[NiC_2O_4][NH_3]^6}

As, NiC_2O_4 is a solid, so its activity is taken as 1 and so for C_2O_4^{2-}

We are given:

[[Ni(NH_3)_6]^{2+}]=0.016M

Putting values in above equations, we get:

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7 0
3 years ago
Which is NOT correct for when the silver and vanadium half-cells are connected via a salt bridge and a potentiometer
lidiya [134]

The question is incomplete, the complete question is

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If we look at the values of reduction potential for the two species, we will discover that vanadium has a negative reduction potential indicating its tendency towards oxidation.

On the other hand, solve has a positive reduction potential indicating a tendency towards reduction.

This implies that vanadium must be oxidized and silver reduced and not the not her way ground? Hence the answer above.

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Explanation:

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7 0
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