How much heat is required to raise the temperature of 65.8 grams of water from 31.5ºC to 46.9ºC?
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Answer : Option 1) The true statement is each carbon-oxygen bond is somewhere between a single and double bond and the actual structure of format is an average of the two resonance forms.
Explanation : The actual structure of formate is found to be a resonance hybrid of the two resonating forms. The actual structure for formate do not switches back and forth between two resonance forms.
The O atom in the formate molecule with one bond and three lone pairs, in the resonance form left with reference to the attached image, gets changed into O atom with two bonds and two lone pairs.
Again, the O atom with two bonds and two lone pairs on the resonance form left, changed into O atom with one bond and three lone pairs. It concludes that each carbon-oxygen bond is neither a single bond nor a double bond; each carbon-oxygen bond is somewhere between a single and double bond.
Also, it is seen that each oxygen atom does not have neither a double bond nor a single bond 50% of the time.
The given equilibrium reaction is,
The given reaction is exothermic. So, heat energy will be a product. Therefore, decreasing the temperature (heat energy) would lead to the formation of more products as when the amount of energy which is a product is reduced, there is more room for the products to form.
Increasing the pressure would shift the equilibrium towards that side which has least number of moles of the gaseous substance. Hence, here increasing the pressure would lead to the formation of more products by shifting the equilibrium towards the right side.
Decreasing the volume would make the equilibrium shift towards the least number of moles of the gaseous substance. So, here in this equilibrium decreasing the volume would lead to the formation of more products.