Answer:
Explanation:
N2(g)+O2(g)⇌2NO(g),
N2(g)+2H2(g)⇌N2H4(g),
2H2O(g)⇌2H2(g)+O2(g),
If we add above reaction we will get:
2N2(g)+2H2O(g)⇌2NO(g)+N2H4(g) Eq (1)
Equilibrium constant for Eq (1) is
Divide Eq (1) by 2, it will become:
N2(g)+H2O(g)⇌NO(g)+1/2N2H4(g) Eq (2)
Equilibrium constant for Eq (2) is
Answer:
The barrier has to be 34.23 kJ/mol lower when the sucrose is in the active site of the enzyme
Explanation:
From the given information:
The activation barrier for the hydrolysis of sucrose into glucose and fructose is 108 kJ/mol.
In this same concentration for the glucose and fructose; the reaction rate can be calculated by the rate factor which can be illustrated from the Arrhenius equation;
Rate factor in the absence of catalyst:
Rate factor in the presence of catalyst:
Assuming the catalyzed reaction and the uncatalyzed reaction are taking place at the same temperature :
Then;
the ratio of the rate factors can be expressed as:
Thus;
Let say the assumed temperature = 25° C
= (25+ 273)K
= 298 K
Then ;
The barrier has to be 34.23 kJ/mol lower when the sucrose is in the active site of the enzyme