Answer:
16.4 °C
Explanation:
Boiling point elevation is the phenomenon in which the boiling point of a solvent will increase when another compound is added to it; meaning that athe resultant solution has a higher boiling point than its pure solvent.
Using the ebullioscopic constant,
ΔT = m * i * Kb
Where,
Δ T is the temperature difference between the boiling point of the solution, Temp.f and boiling point of the pure solvent, Temp.i
Kb is the ebulliscope factor of water = 0.510 °C.kg/mol
i is the van hoffs number = 1
m is the molality in mol/kg.
Calculating the molality of the solution,
Temp.i = 100°C
Temp.f = 104.5 °C
= 4.5/(1*0.510)
= 8.8235 mol/kg
Freezing point depression is defined as the decrease in the freezing point of a solvent on the addition of a solute.
Using the same equation, but kf = 1.86 °C.kg/mol
ΔT = m * i * Kf
Temp.i = freezing point of water = 0°C
Temp.f = (8.8235*1.86) - 0
= 16.412 °C
Freezing point of the solution = 16.4 °C
