Spontaneous at low temperatures.
NO₂ is a brown gas while N₂O₄ is colorless. If heating causes a brown color to persist, then this means that heating causes the reaction to shift backwards and produce NO₂. Therefore, the reaction must be exothermic.
It depends on what type of graph you have. The easiest would be using a H-T diagram. Enthalpy of vaporization is the physical change from liquid to vapor. It occurs at a constant pressure and a constant temperature. As shown in the picture, 1 point is drawn on the subcooled liquid, and another point of the saturated vapor isothermal line. Now, the difference between those two points is the value for the enthalpy of vaporization of water.
Answer:
437.5 kg of first solution and 812.5 kg of second solution should be mixed to get desired solution.
Explanation:
Let the mass of the first solution be x and second solution be y.
Amount solution required = 1250 kg
x + y = 1250 kg....[1]
Percentage of ethanol in required solution = 12% of 1250 kg
Percentage of ethanol in solution-1 = 5% of x
Percentage of ethanol in required solution = 25% of y
5% of x + 25% of y =12% of 1250 kg

x + 5y = 3000 kg...[2]
Solving [1] and [2] we :
x = 437.5 kg , y = 812.5 kg
437.5 kg of first solution and 812.5 kg of second solution should be mixed to get desired solution.