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lidiya [134]
3 years ago
13

The area of the gold electrodes on the quartz crystal microbalance at the opening of Chapter 2 is 3.3 mm^2. One gold electrode i

s covered with DNA at a surface density of 1.2 pmol/cm2. (a) How much mass of the nucleotide cytosine (C) is bound to the surface of the electrode when each bound DNA is elongated by one unit of C
Chemistry
1 answer:
aleksandrvk [35]3 years ago
5 0

This question is incomplete, the complete question is;

The area of the gold electrodes on the quartz crystal microbalance at the opening of Chapter 2 is 3.3 mm^2. One gold electrode is covered with DNA at a surface density of 1.2 pmol/cm2.

(a) How much mass of the nucleotide cytosine (C) is bound to the surface of the electrode when each bound DNA is elongated by one unit of C. The mass formula mass of the bound nucleotide is cytosine + deoxyribose + phosphate = C9H10N3O6P = 287.2 g/mol

Answer: mass of the nucleotide (c) bound is 11.37 g

Explanation:

Given that the area of gold electrodes = 3.3 mm^2

surface density of one gold electrode = 1.2 pmol/cm^2

that is to that in every 1 cm^2 of area, 1.2 pmol DNA is present

therefore

mass of nucleotide present in 3.3 mm^2 is;

= (1.2/100 * 3.3) pmol

= 0.0396 pmol

we were given that formula mass of the bound nucleotide = 287.2 g/mol

so

mass of the nucleotide (c) bound = ( 287.2 * 0.0396 )g

mass of the nucleotide (c) bound =  11.37 g

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1.14 M

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A mysterious white powder could be powdered sugar (C12H22O11), cocaine (C17H21NO4), codeine (C18H21NO3), norfenefrine (C8H11NO2)
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Norfenefrine (C₈H₁₁NO₂).

<h3>Further explanation</h3>

We will solve a case related to one of the colligative properties, namely freezing point depression.

The freezing point of the solution is the temperature at which the solution begins to freeze. The difference between the freezing point of the solvent and the freezing point of the solution is called freezing point depression.

\boxed{ \ \Delta T_f = T_f(solvent) - T_f(solution) \ } \rightarrow \boxed{ \ \Delta T_f = K_f \times molality \ }

<u>Given:</u>

A mysterious white powder could be,

  • powdered sugar (C₁₂H₂₂O₁₁) with a molar mass of 342.30 g/moles,
  • cocaine (C₁₇H₂₁NO₄) with a molar mass of 303.35 g/moles,
  • codeine (C₁₈H₂₁NO₃) with a molar mass of 299.36 g/moles,
  • norfenefrine (C₈H₁₁NO₂) with a molar mass of 153.18 g/moles, or
  • fructose (C₆H₁₂O₆) with a molar mass of 180.16 g/moles.

When 82 mg of the powder is dissolved in 1.50 mL of ethanol (density = 0.789 g/cm³, normal freezing point −114.6°C, Kf = 1.99°C/m), the freezing point is lowered to −115.5°C.

<u>Question: </u>What is the identity of the white powder?

<u>The Process:</u>

Let us identify the solute, the solvent, initial, and final temperatures.

  • The solute = the powder
  • The solvent = ethanol
  • The freezing point of the solvent = −114.6°C
  • The freezing point of the solution = −115.5°C

Prepare masses of solutes and solvents.

  • Mass of solute = 82 mg = 0.082 g
  • Mass of solvent = density x volume, i.e., \boxed{ \ 0.789 \ \frac{g}{cm^3} \times 1.50 \ cm^3 = 1.1835 \ g = 0.00118 \ kg  \ }

We must prepare the solvent mass unit in kg because the unit of molality is the mole of the solute divided by the mass of the solvent in kg.

The molality formula is as follows:

\boxed{ \ m = \frac{moles \ of \ solute}{kg \ of \ solvent} \ } \rightarrow \boxed{ \ m = \frac{mass \ of \ solute \ (g)}{molar \ mass \ of \ solute \times kg \ of \ solvent} \ }

Now we combine it with the formula of freezing point depression.

\boxed{ \ \Delta T_f =  K_f \times \frac{mass \ of \ solute \ (g)}{molar \ mass \ of \ solute \times kg \ of \ solvent} \ }

It is clear that we will determine the molar mass of the solute (denoted by Mr).

We enter all data into the formula.

\boxed{ \ -114.6^0C - (-115.5^0C) = 1.99 \frac{^0C}{m} \times \frac{0.082 \ g}{Mr \times 0.00118 \ kg} \ }

\boxed{ \ 0.9 = \frac{1.99 \times 0.082}{Mr \times 0.00118} \ }

\boxed{ \ Mr = \frac{0.16318}{0.9 \times 0.00118} \ }

We get \boxed{ \ Mr = 153.65 \ }

These results are very close to the molar mass of norfenefrine which is 153.18 g/mol. Thus the white powder is norfenefrine.

<h3>Learn more</h3>
  1. The molality and mole fraction of water brainly.com/question/10861444
  2. About the mass and density of ethylene glycol as an  antifreeze brainly.com/question/4053884
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