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Dmitry_Shevchenko [17]
3 years ago
6

How many acidic H+ ion is given by H3BO3 in aqueous solution?? ...?

Chemistry
1 answer:
notka56 [123]3 years ago
7 0
Boric acid, H3BO3, in aqueous solution would only give out one H+ ion. As it is also produce OH ion and by hydrolysis it produces one proton. <span>All the boron compounds (BX3) are having only 6 valence electrons in it and should follow the octet rule by taking another electron.</span>
 
B(OH)3 + 2 H2O → B(OH)4− + H3O
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Answer : The work, heat during the process and the change of entropy of the gas are, 0 J, 3333.003 J and -10 J respectively.

Explanation :

(a) At constant volume condition the entropy change of the gas is:

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We know that,

The relation between the C_p\text{ and }C_v for an ideal gas are :

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As we are given :

C_p=28.253J/K.mole

28.253J/K.mole-C_v=8.314J/K.mole

C_v=19.939J/K.mole

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\Delta S=-n\times C_v\ln \frac{T_2}{T_1}

\Delta S=-2.388\times 19.939J/K.mole\ln \frac{369.5K}{299.5K}=-10J

(b) As we know that, the work done for isochoric (constant volume) is equal to zero. (w=-pdV)

(C) Heat during the process will be,

q=n\times C_v\times (T_2-T_1)=2.388mole\times 19.939J/K.mole\times (369.5-299.5)K= 3333.003J

Therefore, the work, heat during the process and the change of entropy of the gas are, 0 J, 3333.003 J and -10 J respectively.

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