2.565L
Explanation:
- Charles law states that the volume of an ideal gas at constant pressure is directly proportional to the absolute temperature.V/T=K
 
          V1/T1=V2/T2        
           Unit of Kelvin = 273.15
-  To get the absolute temperature, we need to convert the degree celsius temperature to kelvin. 
 
           T1= 22+273.15= 295.15 K
           T2 = 71+273.15= 344.15 K
           V1 = 2.20 L
           V2 =?
           2.20/295.15=V2/344.15
           0.00745 x 344.15 = 2.565 L
Hence,  2.565 L is the new volume of the balloon.
 
        
             
        
        
        
Answer: 1) 
Equilibrium constant is defined as the ratio of the product of concentration of products to the product of concentration of reactants each term raised to their stochiometric coefficients.
![K_{eq}=\frac{[H_2S]^2}{H_2]^2\times [S_2]}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BH_2S%5D%5E2%7D%7BH_2%5D%5E2%5Ctimes%20%5BS_2%5D%7D)
where [] = concentration in Molarity=
Thus ![[H_2S]=\frac{68.5}{1.0}=68.5M](https://tex.z-dn.net/?f=%5BH_2S%5D%3D%5Cfrac%7B68.5%7D%7B1.0%7D%3D68.5M)
![[H_2]=\frac{0.50}{1.0}=0.50M](https://tex.z-dn.net/?f=%5BH_2%5D%3D%5Cfrac%7B0.50%7D%7B1.0%7D%3D0.50M)
![[S_2]=\frac{0.020}{1.0}=0.020M](https://tex.z-dn.net/?f=%5BS_2%5D%3D%5Cfrac%7B0.020%7D%7B1.0%7D%3D0.020M)
![K_{eq}=\frac{[68.5]^2}{0.50]^2\times [0.020]}=938450](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5B68.5%5D%5E2%7D%7B0.50%5D%5E2%5Ctimes%20%5B0.020%5D%7D%3D938450)
As the value of K is greater than 1, the reaction is product favored.
2) 
![K_{eq}=\frac{[NO_2]^2}{[N_2O_4]}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BNO_2%5D%5E2%7D%7B%5BN_2O_4%5D%7D)
![K_{eq}=\frac{[0.500]^2}{[0.0250]}=10](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5B0.500%5D%5E2%7D%7B%5B0.0250%5D%7D%3D10)
3) 
![K_{eq}=\frac{[NH_3]^2}{[N_2]\times [H_2]^3}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BNH_3%5D%5E2%7D%7B%5BN_2%5D%5Ctimes%20%5BH_2%5D%5E3%7D)
4) Reactions which do not continue to completion are called equilibrium reactions as the rate of forward reaction is equal to the rate of backward direction.
 
        
                    
             
        
        
        
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Below are the answers:
1.b - cfcs
2.d - <span>carbon dioxide,smog,acid rain. </span>
3.a - <span> laws and treaties that limit or ban pollutants</span>
4.c - <span>burning leaves and brush
</span>
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