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Vlad [161]
3 years ago
5

Which of the following reactions should have the larger emf under standard conditions? Why?

Chemistry
1 answer:
miskamm [114]3 years ago
7 0

Answer:

Cu(NO3)2(aq)+Pb(s) ⇌ Pb(NO3)2(aq)+Cu(s)

Explanation:

If we look at the both reactions closely, we will quickly discover that the reaction CuSO4(aq)+Pb(s) ⇌ PbSO4(s)+Cu(s) involves PbSO4.

The compound PbSO4 is insoluble in water and sinks to the bottom of the reaction vessel. When this occurs, the concentration of Pb^2+ becomes low. This will bring about a low voltage in the cell.

On the other hand, Pb(NO3)2 is soluble in water hence the cell voltage in this case is higher than the former.

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Sometimes in lab we collect the gas formed by a chemical reaction over water (see sketch at right). This makes it easy to isolat
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Answer:

The correct answer is 0.00582 grams.

Explanation:

In order to solve the question, let us consider the vapor pressure of H2O, as hydrogen gas is collected over water, therefore, we have to consider the vapor pressure of water in the given case. Let us assume that the pressure is 760 torr or 1 atm.

It is known that the vapor pressure of water at 40 degree C is 53.365 torr (Based on the data).

Therefore, the pressure of H2 will be,

P = 760-55.365 = 704.635 torr or 704.635/760 = 0.9272 atm

The volume of the hydrogen gas collected in the tube is 80 ml or 0.08 L

Temperature in Kelvin will be 40+273 = 313 K

To calculate the moles of hydrogen (H2) gas, there is a need to use the ideal gas equation, that is, PV= nRT, in this R is the gas constant, whose value is 0.0821 L atm/molK, and n is the moles of the gas.

By inserting the values in the equation we get:

PV = nRT

n = PV/RT = 0.9272 *0.08 / 0.0821 * 313

n = 0.00289 moles

The mass of H2 will be moles * molar mass = 0.00289 * 2.016

= 0.00582 grams.

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