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sweet [91]
3 years ago
11

Magnesium (used in the manufacture of light alloys) reacts with iron(III) chloride to form magnesium chloride and iron. 3Mg(s) +

2FeCl₃(s) → 3MgCl₂(s) + 2Fe(s) A mixture of 41.0 g of magnesium ( = 24.31 g/mol) and 175 g of iron(III) chloride ( = 162.2 g/mol) is allowed to react. Identify the limiting reactant and determine the mass of the excess reactant present in the vessel when the reaction is complete.
Chemistry
1 answer:
Paladinen [302]3 years ago
4 0

Answer:

Theanswer to your question is:

Limiting reactant = FeCl₃

Excess reactant = 1.66 g of Mg

Explanation:

Data

Mg = 41 g   = 24.31 g/mol

FeCl₃ = 175 g = 162.2 g/mol

                         3Mg(s) + 2FeCl₃(s) → 3MgCl₂(s) + 2Fe(s)

                      3(24.31) of Mg ------------------  2(162.2)  of FeCl₃

                      72.93 g of Mg ------------------ 324.4 g of FeCl₃

Theoretical Proportion = 324.4/72.93 = 4.44

Practical proportion   =  175 / 41 = 4.2

As the proportion disminishes the limiting reactant is FeCl₃.

Excess reactant

                               72.93 g of Mg ------------------ 324.4 g of FeCl₃

                                   x -------------------------           175 g of FeCl₃

x = (175 x 72.93) / 324.4

x = 39.34 g of Mg

Excess = 41 - 39.34

           = 1.66 g of Mg

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Answer:

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1) ΔG°r = ∑νiΔG°f,i

⇒ ΔG°r(298 K) = ΔG°CO2(g) + ΔG°H2(g) - ΔG°H2O(g) - ΔG°CO(g)

from literature, T = 298 K:

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2) K = e∧(-ΔG°/RT)

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assuming T = 200 K

⇒ ΔG°r(200 K) = - (8.314 E-3)(200)Ln(9.624E-3)

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