Those two are correct, your just missing A.
<u>Answer:</u> The tree was burned 16846.4 years ago to make the ancient charcoal
<u>Explanation:</u>
The equation used to calculate rate constant from given half life for first order kinetics:

where,
= half life of the reaction = 5715 years
Putting values in above equation, we get:

Rate law expression for first order kinetics is given by the equation:
![k=\frac{2.303}{t}\log\frac{[A_o]}{[A]}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B2.303%7D%7Bt%7D%5Clog%5Cfrac%7B%5BA_o%5D%7D%7B%5BA%5D%7D)
where,
k = rate constant = 
t = time taken for decay process = ? yr
= initial amount of the sample = 100 grams
[A] = amount left after decay process = 13 grams
Putting values in above equation, we get:

Hence, the tree was burned 16846.4 years ago to make the ancient charcoal
Answer:
Explanation: The strengths of the inter molecular forces varies as follows -

The normal boiling point of CSe2 is 125°C and that of CS2 is 116°C, which explains the trend that as we move down the group, the boiling point of e compound increases as the size increases.
This usually happens because larger and heavier atoms have a tendency to exhibit greater inter molecular strengths due to the increase in size . As the size increases, the valence shell electrons move far away from the nucleus, thus has a greater tendency to attract the temporary dipoles.
And larger the inter molecular forces, more tightly the electrons will be held to each other and thus more thermal energy would be required to break the bonds between them.
We can use combined gas laws to solve for the volume of the gas

where P - pressure, V - volume , T - temperature and k - constant

parameters for the first instance are on the left side and parameters for the second instance are on the right side of the equation
T1 - temperature in Kelvin - 20 °C + 273 = 293 K
T2 - 40 °C + 273 = 313 K
substituting the values

V = 17.8 L
volume of the gas is 17.8 L