Determine a detailed mechanism for the chlorination of benzene using cl2 and fecl3.
1 answer:
Step (1):
Generation of electrophile: by the action of Lewis acid FeCl₃ on Cl₂ to serve as a source of Cl⁺ (Electrophile)
Step (2):
Addition of electrophile to form carbocation:
addition of electrophile to form C-Cl bond and form carbocation which is stabilized by resonance.
Step (3):
Loss of proton to re-form the aromatic ring by the action of FeCl₄⁻ which removes proton from carbon containing Cl and forming the aromatic ring again
Generation of electrophile: by the action of Lewis acid FeCl₃ on Cl₂ to serve as a source of Cl⁺ (Electrophile)
Step (2):
Addition of electrophile to form carbocation:
addition of electrophile to form C-Cl bond and form carbocation which is stabilized by resonance.
Step (3):
Loss of proton to re-form the aromatic ring by the action of FeCl₄⁻ which removes proton from carbon containing Cl and forming the aromatic ring again
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<u>Answer:</u> The theoretical yield of iron(III) sulfate is 26.6 grams
<u>Explanation:</u>
To calculate the number of moles, we use the equation:
.....(1)
Given mass of iron(III) phosphate = 20.00 g
Molar mass of iron(III) phosphate = 150.82 g/mol
Putting values in equation 1, we get:
The given chemical equation follows:
As, sodium sulfate is present in excess. So, it is considered as an excess reagent.
Thus, iron(III) phosphate is considered as a limiting reagent because it limits the formation of product.
By Stoichiometry of the reaction:
2 moles of iron(III) phosphate produces 1 mole of iron(III) sulfate
So, 0.133 moles of iron(III) phosphate will produce = of iron(III) sulfate
Now, calculating the mass of iron(III) sulfate from equation 1, we get:
Molar mass of iron(III) sulfate = 399.9 g/mol
Moles of iron(III) sulfate = 0.0665 moles
Putting values in equation 1, we get:
Hence, the theoretical yield of iron(III) sulfate is 26.6 grams
Answer:
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