Answer:
pH = 12.15
Explanation:
To determine the pH of the HCl and KOH mixture, we need to know that the reaction is a neutralization type.
HCl + KOH → H₂O + KCl
We need to determine the moles of each compound
M = mmol / V (mL) → 30 mL . 0.10 M = 3 mmoles of HCl
M = mmol / V (mL) → 40 mL . 0.10 M = 4 mmoles of KOH
The base is in excess, so the HCl will completely react and we would produce the same mmoles of KCl
HCl + KOH → H₂O + KCl
3 m 4 m -
1 m 3 m
As the KCl is a neutral salt, it does not have any effect on the pH, so the pH will be affected, by the strong base.
1 mmol of KOH has 1 mmol of OH⁻, so the [OH⁻] will be 1 mmol / Tot volume
[OH⁻] 1 mmol / 70 mL = 0.014285 M
- log [OH⁻] = 1.85 → pH = 14 - pOH → 14 - 1.85 = 12.15
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Explanation:
(missing in Q) : Calculate the concentration of CO & H2 & H2O when the system returns the equilibrium???
when the reaction equation is:
C(s) + H2O(g) ↔ H2(g) + CO(g)
∴ Kc = [H2] [CO] / [H2O]
and we have Kc = 0.0393 (given missing in the question)
when the O2 is added so, the reaction will be:
2H2(g) + O2(g) → 2H2O(g)
that means that 0.15 mol H2 gives 0.15 mol of H2O
∴ by using ICE table:
[H2O] [H2] [CO]
initial 0.57 + 0.15 0 0.15
change -X +X +X
Equ (0.72-X) X (0.15+X)
by substitution:
0.0393 = X (0.15+X) / (0.72-X) by solving for X
∴ X = 0.098
∴[H2] = X = 0.098 M
∴[CO] = 0.15 + X
= 0.15 + 0.098 = 0.248 M
∴[H2O] = 0.72 - X
= 0.72 - 0.098
= 0.622 M