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Kryger [21]
3 years ago
14

A sample of ammonia gas was allowed to come to equilibrium at 400 K. 2NH3(g) <---> N2(g) 3H2(g) At equilibrium, it was fou

nd that the concentration of H2 was 0.0551 M, the concentration of N2 was 0.0183 M, and the concentration of NH3 was 0.383 M. What is Kc for this equilibrium
Chemistry
1 answer:
Softa [21]3 years ago
8 0

Answer:

Kc for this equilibrium is 2.30*10⁻⁶

Explanation:

Equilibrium occurs when the rate of the forward reaction equals the rate of the reverse reaction and the concentrations of reactants and products are held constant.

Being:

aA + bB ⇔ cC + dD

the equilibrium constant Kc is defined as:

Kc=\frac{[C]^{c}*[D]^{d}  }{[A]^{a} *[B]^{b} }

In other words, the constant Kc is equal to the multiplication of the concentrations of the products raised to their stoichiometric coefficients by the multiplication of the concentrations of the reactants also raised to their stoichiometric coefficients. Kc is constant for a given temperature, that is to say that as the reaction temperature varies, its value varies.

In this case, being:

2 NH₃(g) ⇔ N₂(g) + 3 H₂(g)

the equilibrium constant Kc is:

Kc=\frac{[N_{2} ]*[H_{2} ]^{3}  }{[NH_{3} ]^{2} }

Being:

  • [N₂]= 0.0551 M
  • [H₂]= 0.0183 M
  • [NH₃]= 0.383 M

and replacing:

Kc=\frac{0.0551*0.0183^{3}  }{0.383^{2} }

you get:

Kc= 2.30*10⁻⁶

<u><em>Kc for this equilibrium is 2.30*10⁻⁶</em></u>

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Answer:

You must add 48.97 mL of water to make the 0.200 M diluted solution.

Explanation:

In chemistry, dilution is the reduction in concentration of a chemical in a solution. In other words, it is the process of reducing the concentration of solute in solution, simply adding more solvent to the solution.

In a dilution, the quantity or mass of the solute is not changed but only that of the solvent. As only solvent is being added, by not increasing the amount of solute the concentration of the solute decreases.

The expression for the dilution calculations is:

Cinitial* Vinitial = Cfinal* Vfinal

In this case:

  • Cinitial= 12 M
  • Vinitial= 0.830 mL
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Replacing:

12 M*0.830 mL= 0.200 M*Vfinal

Solving:

Vfinal=\frac{12 M*0.830 mL}{0.200 M}

Vfinal= 49.8 mL

Since 0.830 mL is the volume you initially have of HCl, the amount of water you must add is:

49.8 mL - 0.830 mL= 48.97 mL

<u><em>You must add 48.97 mL of water to make the 0.200 M diluted solution.</em></u>

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Explanation:

It is known that equation for ideal gas is as follows.

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     Volume, V = 2.4 cubic ft,      R = 10.73 psia ft^{3}/lb mol R

Also, we know that number of moles is equal to mass divided by molar mass of the gas.

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  • Now, calculate the specific gravity of the gas as follows.

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