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VikaD [51]
3 years ago
11

"Pure acetic acid (HC2H3O2) is a liquid and is known as glacial acetic acid. Calculate the molarity of a solution prepared by di

ssolving 5.00 mL of glacial acetic acid at 25 °C in sufficient water to give 500.0 mL of solution. The density of glacial acetic acid at 25 °C is 1.05 g/mL. Pure acetic acid (HC2H3O2) is a liquid and is known as glacial acetic acid. Calculate the molarity of a solution prepared by dissolving 5.00 mL of glacial acetic acid at 25 °C in sufficient water to give 500.0 mL of solution. The density of glacial acetic acid at 25 °C is 1.05 g/mL.
A. 3.50 × 10-5 M
B. 126 M
C. 0.0350 M
D. 2.10 M
E. 2.10 × 10-3 M
Chemistry
1 answer:
musickatia [10]3 years ago
5 0

<u>Answer:</u> The molarity of glacial acetic acid is 0.175 M

<u>Explanation:</u>

To calculate the mass of acetic acid, we use the equation:

\text{Density of substance}=\frac{\text{Mass of substance}}{\text{Volume of substance}}

Density of acetic acid = 1.05 g/mL

Volume of acetic acid = 5.00 mL

Putting values in above equation, we get:

1.05g/mL=\frac{\text{Mass of acetic acid}}{5.00mL}\\\\\text{Mass of acetic acid}=(1.05g/mL\times 5.00mL)=5.25g

To calculate the molarity of solution, we use the equation:

\text{Molarity of the solution}=\frac{\text{Mass of solute}\times 1000}{\text{Molar mass of solute}\times \text{Volume of solution (in mL)}}

We are given:

Mass of solute (acetic acid) = 5.25 g

Molar mass of acetic acid = 60.052 g/mol

Volume of solution = 500.0 mL

Putting values in above equation, we get:

\text{Molarity of solution}=\frac{5.25g\times 1000}{60.052g/mol\times 500.0mL}\\\\\text{Molarity of solution}=0.175M

Hence, the molarity of glacial acetic acid is 0.175 M

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1.00 M CaCl2 Density = 1.07 g/mL
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Explanation:

Molarity of solution = 1.00 M = 1.00 mol/L

In 1 L of solution 1.00 moles of calcium chloride is present.

Mass of solute or calcium chloride = m

m = 1 mol\times 111 g/mol = 111 g

Mass of solution = M

Volume of solution = V = 1L = 1000 mL

Density of solution , d= 1.07 g/mL

M=d\times V=1.07 g/mL\times 1000 mL=1,070 g

1) The value of %(m/M):

\frac{m}{M}\times 100=\frac{111 g}{1,070 g}\times 100=10.37\%

2) The value of %(m/V):

\frac{m}{V}\times 100=\frac{111 g}{1000 L}\times 100=11.1\%

Molality = \frac{\text{Moles of compound }}{\text{mass of solvent in kg}}

Normality=\frac{\text{Moles of compound }}{n\times \text{volume of solution in L}}

n = Equivalent mass

n = \frac{\text{molar mass of ion}}{\text{charge on an ion}}

3) Normality of calcium ions:

Moles of calcium ion = 1 mol (1 CaCl_2 mole has 1 mole of calcium ion)

n=\frac{40 g/mol}{2}=20

=\frac{1 mol}{20 g/mol\times 1L}=0.050 N

4) Normality of chlorine ions:

Moles of chlorine ion = 2 mol (1 CaCl_2 mole has 2 mole of chlorine ion)

n=\frac{35.5 g/mol}{1}=35.5

=\frac{2 mol}{35.5 g/mol\times 1L}=0.056 N

Moles of calcium chloride = 1.00 mol

Mass of solvent =  Mass of solution - mass of solute

= 1,070 g - 111 g = 959  g = 0.959 kg ( 1 g =0.001 kg)

5) Molality of the solution :

\frac{1 mol}{0.959 kg}=1.043 mol/kg

Moles of calcium chloride = n_1=1mol

Mass of solvent = 959 g

Moles of water = n_2=\frac{959 g}{18 g/mol}=53.28 mol

Mass of solvent = 959 g

6) Mole fraction of calcium chloride =

\chi_1=\frac{n_1}{n_1+n_2}=\frac{1mol}{1 mol+53.28 mol}=0.01842

7) Mole fraction of water =

\chi_2=\frac{n_2}{n_1+n_2}=\frac{53.28 mol}{1mol+53.28 mol}=0.9816

8) Mass of solution = m'

Volume of the solution= v = 100 mL

Density of solution = d = 1.07 g/mL

m'=d\times v=1.07 g/ml\times 100 g= 107 g

Mass of 100 mL of this solution 107 grams of solution.

9) Volume of solution = V = 100 mL

Mass of solution = M'' = 107 g

Mass of solute = m

The value of %(m/V) of solution = 11.1%

11.1\%=\frac{m}{100 mL}\times 100

m = 11.1 g

Mass of solvent = M''- m = 107 g -11.1 g = 95.9 g

95.9 grams of water was present in 100 mL of given solution.

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