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Allushta [10]
3 years ago
13

Kp is the equilibrium constant for dissociation of the propionic acid dimer. what is the sign of the slope for a plot of the nat

ural logarithm of kp vs. inverse temperature for this reaction?
Chemistry
1 answer:
sveta [45]3 years ago
6 0

Ans: The sign of the slope is negative

The free energy change (ΔG) is related to the equilibrium constant Kp as:

ΔG = -RTlnKp -------(1)

Also, ΔG = ΔH-TΔS ------(2)

therefore,

-RTlnKp = ΔH-TΔS

ln(Kp) = -ΔH/R(1/T) + ΔS/R

Thus, a plot of lnKp Vs 1/T will give a straight line with a negative slope such that:

Slope = -ΔH/R

Intercept = ΔS/R

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What’s the difference between heterogeneous and homogeneous mixtures?
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5 0
3 years ago
Zinc metal reacts with hydrochloric acid to produce zinc(II) chloride and hydrogen gas. How many liters of hydrogen gas will be
AleksAgata [21]

Answer:

0.120 L of hydrogen gas will be produced

Explanation:

Step 1: Data given

Mass of zinc = 10.0 grams

Volume of hydrochloric acid = 23.8 mL

Molarity of hydrochloric acid = 0.45 M

Molar mass of zinc =65.38 g/mol

Step 2: The balanced equation

Zn + 2HCl → ZnCl2 + H2

Step 3: Calculate moles Zinc

Moles Zn = mass Zn / molar mass Zn

Moles Zn = 10.0 grams / 65.38 g/mol

Moles Zn  =  0.153 moles

Step 4: Calculate moles HCl

Moles HCl = molarity * volume

Moles HCl = 0.45 M * 0.0238 L

Moles HCl = 0.01071 moles

Step 5: Calculate limiting reactant

For 1 mol Zn, we need 2 moles HCl to produce 1 mol ZnCl2 and 1 mol H2

HCl is the limiting reactant. It will completely be consumed (0.01071 moles)

Zn is in excess. There will react 0.01071/2 = 0.005355 moles

There will remain 0.153 - 0.005355 = 0.147645 moles

Step 6: Calculate moles H2

For 1 mol Zn, we need 2 moles HCl to produce 1 mol ZnCl2 and 1 mol H2

For 0.01071 moles HCl we'll have 0.005355 moles H2

Step 7: Calculate volume H2

1 mol at STP = 22.4 L

0.005355 moles = 22.4 * 0.005355 = 0.120 L = 120 mL

0.120 L of hydrogen gas will be produced

4 0
3 years ago
All atoms of a given element are identical was proven wrong because of the existence or
vagabundo [1.1K]

Answer:

they are all similar

Explanation:

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