Answer:
P1V1= P2V2
Explanation:
Inverse relationship
V2 = V1 X P1/P2
V2= 14.3 L x 45.0 mm Hg/63.0 mmHg= 8.99
When the concentration of a reactant is increased, the chemical equilibrium will shift towards the products. More product is formed and the concentration of the reactants decreases as the concentration of the products increases.
Answer:
37 mmol of acetate need to add to this solution.
Explanation:
Acetic acid is an weak acid. According to Henderson-Hasselbalch equation for a buffer consist of weak acid (acetic acid) and its conjugate base (acetate)-
![pH=pK_{a}(acetic acid)+log[\frac{mmol of CH_{3}COO^{-}}{mmol of CH_{3}COOH }]](https://tex.z-dn.net/?f=pH%3DpK_%7Ba%7D%28acetic%20acid%29%2Blog%5B%5Cfrac%7Bmmol%20of%20CH_%7B3%7DCOO%5E%7B-%7D%7D%7Bmmol%20of%20CH_%7B3%7DCOOH%20%7D%5D)
Here pH is 5.31, 
(acetic acid) is 4.74 and number of mmol of acetic acid is 10 mmol.
Plug in all the values in the above equation:
![5.31=4.74+log[\frac{mmol of CH_{3}COO^{-}}{10}]](https://tex.z-dn.net/?f=5.31%3D4.74%2Blog%5B%5Cfrac%7Bmmol%20of%20CH_%7B3%7DCOO%5E%7B-%7D%7D%7B10%7D%5D)
or, mmol of 
= 37
So 37 mmol of acetate need to add to this solution.
Balance each one by adding electrons to make the charges on both sides the same:
Sn--> Sn2+ + 2 e-
Ag+ + 1 e- --> Ag
Now, you have to have the same number of electrons in the two half-reactions, so multiply the second one by 2 to get:
2 Ag+ + 2 e- --> 2 Ag
Now, just add the two half reactions together, cancelling anything that's the same on both sides:
2 Ag+ + Sn --> Sn2+ + 2 Ag
And you're done.
