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jolli1 [7]
3 years ago
6

Consider the reaction C2H4(g) + H2O(g) --> CH3CH2OH(g)

Chemistry
1 answer:
arsen [322]3 years ago
6 0

Answer:

K = 361.369

Explanation:

C2H4(g) + H2O(g) → CH3CH2OH(g)

∴ ΔG°f(298.15K) CH3CH2OH(g) = - 174.8 KJ/mol

∴ ΔG°f(298.15) C2H4(g) =  68.4 KJ/mol

∴ ΔG°f(298.15) H2O(g) = - 228.6 KJ/mol

⇒ ΔG°f(298.15) = - 174.8 - ( - 228.6 + 68.4 ) = - 14.6 KJ/mol

  • K = e∧(-ΔG°f / RT)

∴ R = 8.314 E-3 KJ/mol.K

∴ T = 298.15 K

⇒ K = e∧(-(-14.6)/((8.314 E-3)(298.15)))

⇒ K = e∧(5.889)

⇒ K = 361.369

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To make the ratio as a whole number multiply numerator and denominator by 4.

Ratio of  C : H =  \frac{1\times4}{2.25\times4} = 4 : 9

The mole ratio of the element is repersented by subscripts in emperical formula.

Therefore, the Emperical formula = C_{4} H_{9}



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