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algol13
3 years ago
14

The energy exchange with the environment during a chemical reaction is called the heat of reaction.

Chemistry
1 answer:
JulijaS [17]3 years ago
6 0
This is a hard question
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Use the standard reaction enthalpies given below to determine ΔH°rxn for the following reactionP4(g) + 10 Cl2(g) → 4PCl5(s) ΔH°r
weqwewe [10]

Answer:

Therefore  \bigtriangledown H^\circ_{rxn}= -1835 KJ

Explanation:

Enthalpy is denoted by H.

Enthalpy: Total heat change in a chemical reaction is called enthalpy.

The change of entalpy of a reaction is denoted by \bigtriangledown H^\circ_{rxn}

Hass's Law:The change in enthalpy of any process can be determined by calculating the sum of change in enthalpy of each of the steps involved in the process.

g= gas

S= solid

P₄(g)+10Cl₂(g)→ 4Cl₅(s)       \bigtriangledown H^\circ_{rxn}=?

PCl₅(s)→ PCl₃(g)+Cl₂(g) .......(1)       \bigtriangledown H^\circ_{rxn}= +157KJ

P₄(g)+6Cl₂(g)→  4PCl₃(g).............(2)     \bigtriangledown H^\circ_{rxn}= -1207 KJ

If we flip a reaction the value of enthalpy will be change positive to negative or nagative to positive but the numerical value will be remain same.

We need rearrange the equation (1) because in the required equation Cl₂ is on the left side. So we flip the first equation.

PCl₃(g)+Cl₂(g)→PCl₅(s)......(3)          \bigtriangledown H^\circ_{rxn}= -157KJ

Multiplying 4 with equation (3)

4 PCl₃(g)+4Cl₂(g)→4PCl₅(s)......(4)          \bigtriangledown H^\circ_{rxn}=4×( -157)KJ= -628 KJ

Adding equation (2) and (4) we get

P₄(g)+6Cl₂(g)+4 PCl₃(g)+4Cl₂(g)→4PCl₃(g)+4PCl₅(s)    \bigtriangledown H^\circ_{rxn}=( -1207-628)KJ

⇒P₄(g)+10Cl₂(g)→4PCl₃(g)-4PCl₃(g)+4PCl₅(s)      \bigtriangledown H^\circ_{rxn}= - 1835KJ

⇒P₄(g)+10Cl₂(g)→ 4Cl₅(s)       \bigtriangledown H^\circ_{rxn}= -1835 KJ

Therefore  \bigtriangledown H^\circ_{rxn}= -1835 KJ

5 0
2 years ago
Urea, CH4N2O (s), is manufactured from NH3 (g) and CO2 (g). H2O (l) is another product of this reaction. An experiment is starte
Katarina [22]

Answer:

a. 4.41 g of Urea

b. 1.5 g of Urea

Explanation:

To start the problem, we define the reaction:

2NH₃ (g) +  CO₂ (g) → CH₄N₂O (s)  +  H₂O(l)

We only have mass of ammonia, so we assume the carbon dioxide is in excess and ammonia is the limiting reactant:

2.6 g . 1mol / 17g = 0.153 moles of ammonia

Ratio is 2:1. 2 moles of ammonia can produce 1 mol of urea

0.153 moles ammonia may produce, the half of moles

0153 /2 = 0.076 moles of urea

To state the theoretical yield we convert moles to mass:

0.076 mol . 58 g/mol = 4.41 g

That's the 100 % yield reaction

If the percent yield, was 34%:

4.41 g . 0.34 = 1.50 g of urea were produced.

Formula is (Yield produced / Theoretical yield) . 100 → Percent yield

3 0
3 years ago
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