Solids are packed together closely, liquids are farther apart but still relatively close, and gases are very far apart with lots of space.
The alcohol on board is cognac 2
The ideal gas under STP is 22.4 L/mol. While the gas has a rule of P1V1/T1=P2V2/T2. So the volume under 101 kPa and 273 K is 0.2*22.4=4.48 L.