The freezing point depression is calculated through the equation,
ΔT = (kf) x m
where ΔT is the difference in temperature, kf is the freezing point depression constant (1.86°C/m), and m is the molality. Substituting the known values,
5.88 = (1.86)(m)
m is equal to 3.16m
Recall that molality is calculated through the equation,
molality = number of mols / kg of solvent
number of mols = (3.16)(1.25) = 3.95 moles
Then, we multiply the calculated amount in moles with the molar mass of ethylene glycol and the answer would be 244.9 g.
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The major limitations of Newlands' law of octaves were : (i) It was applicable to only lighter elements having atomic masses upto 40 u, i.e., upto calcium. After calcium, the first and the eighth element did not have similar properties