Answer:
The presence of 1-2% ethanol as catalyst, suppresses the oxidation of chloroform with oxygen to give a poisonous gas called phosgene. ... Here glycerol acts as negative catalyst. Criteria or characteristics of catalysts. i. The mass and chemical composition of catalyst should remain unchanged at the end of the reaction.
Explanation:
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We can use the ideal gas equation:
PV = nRT
P = 202.6kPa = 202600 Pa (You have to
multiply by 1000)
n = 0.050 mole
R = 0.082 atm*l/(K*mol)
T = 400K
We will have to convert from Pa to atm or
viceversa.
101325 Pa________1 atm
202600 Pa________x = 2.00 atm
2atm*V = 0.050 mole*0.082 atm*l/(K*mol)* 400K
V = 0.050 mole*0.082 atm*l/(K*mol)* 400K/2atm
= 0.82 liters = 820 mililiters
