ΔHrxn = ΣδΗ(bond breaking) - ΣδΗ(bond making)
Bond enthalpies,
N ≡ N ⇒ 945 kJ mol⁻¹
N - Cl ⇒ 192 kJ mol⁻¹
Cl - Cl⇒ 242 kJ mol⁻¹
According to the balanced equation,
ΣδΗ(bond breaking) = N ≡ N x 1 + Cl - Cl x 3
= 945 + 3(242)
= 1671 kJ mol⁻¹
ΣδΗ(bond making) = N - Cl x 3 x 2
= 192 x 6
= 1152 kJ mol⁻¹
δHrxn = ΣδΗ(bond breaking) - ΣδΗ(bond making)
= 1671 kJ mol⁻¹ - 1152 kJ mol⁻¹
= 519 kJ mol⁻¹
Answer:
34.28 L ( 1.5*22.4 L)
Explanation:
Calculation of the moles of aluminum as:-
Mass = 55 g
Molar mass of aluminum = 26.981539 g/mol
The formula for the calculation of moles is shown below:
Thus,

According to the reaction:-

4 moles of aluminum react with 3 moles of oxygen gas
1 mole of aluminum react with
moles of oxygen gas
2.0384 moles of aluminum react with
moles of oxygen gas
Moles of oxygen gas = 1.5288 moles
At STP,
Pressure = 1 atm
Temperature = 273.15 K
Using ideal gas equation as:

where,
P is the pressure
V is the volume
n is the number of moles
T is the temperature
R is Gas constant having value = 0.0821 L.atm/K.mol
Applying the equation as:
1 atm × V = 1.5288 mol × 0.0821 L.atm/K.mol × 273.15 K
⇒V = 34.28 L ( 1.5*22.4 L)
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