What expression approximates the volume of O2 consumed, measure at STP, when 55 g of Al reacts completely with excess O2?2 Al(s)
1 answer:
Answer:
34.28 L ( 1.5*22.4 L)
Explanation:
Calculation of the moles of aluminum as:-
Mass = 55 g
Molar mass of aluminum = 26.981539 g/mol
The formula for the calculation of moles is shown below:
Thus,
According to the reaction:-
4 moles of aluminum react with 3 moles of oxygen gas
1 mole of aluminum react with moles of oxygen gas
2.0384 moles of aluminum react with moles of oxygen gas
Moles of oxygen gas = 1.5288 moles
At STP,
Pressure = 1 atm
Temperature = 273.15 K
Using ideal gas equation as:
where,
P is the pressure
V is the volume
n is the number of moles
T is the temperature
R is Gas constant having value = 0.0821 L.atm/K.mol
Applying the equation as:
1 atm × V = 1.5288 mol × 0.0821 L.atm/K.mol × 273.15 K
⇒V = 34.28 L ( 1.5*22.4 L)
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Answer : The only reaction (C) that shows that the same reactant undergoes both oxidation and reduction.
Explanation :
Disproportionation reaction : It is defined as the reaction in which the same reactant undergoes both oxidation and reduction reaction. It is a redox reaction.
Redox reaction or Oxidation-reduction reaction : It is defined as the reaction in which the oxidation and reduction reaction takes place simultaneously.
Oxidation reaction : It is defined as the reaction in which a substance looses its electrons. In this, oxidation state of an element increases. Or we can say that in oxidation, the loss of electrons takes place.
Reduction reaction : It is defined as the reaction in which a substance gains electrons. In this, oxidation state of an element decreases. Or we can say that in reduction, the gain of electrons takes place.
(A) The given balanced reaction is,
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This reaction is a redox reaction but not disproportionation reaction because in this reaction there are two reactants in which sulfur shows oxidation and oxygen shows reduction.
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This reaction is a disproportionation reaction because in this reaction only one reactant bromine that shows both oxidation and reduction reaction.
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(E) The given balanced reaction is,
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i. The dissolution of PbSO₄ in water entails its ionizing into its constituent ions:
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ii. Given the dissolution of some substance
,
the Ksp, or the solubility product constant, of the preceding equation takes the general form
.
The concentrations of pure solids (like substance A) and liquids are excluded from the equilibrium expression.
So, given our dissociation equation in question i., our Ksp expression would be written as:
.
---
iii. Presumably, what we're being asked for here is the <em>molar </em>solubility of PbSO4 (at the standard 25 °C, as Ksp is temperature dependent). We have all the information needed to calculate the molar solubility. Since the Ksp tells us the ratio of equilibrium concentrations of PbSO4 in solution, we can consider either [Pb2+] or [SO4^2-] as equivalent to our molar solubility (since the concentration of either ion is the extent to which solid PbSO4 will dissociate or dissolve in water).
We know that Ksp = [Pb2+][SO4^2-], and we are given the value of the Ksp of for PbSO4 as 1.3 × 10⁻⁸. Since the molar ratio between the two ions are the same, we can use an equivalent variable to represent both:
So, the molar solubility of PbSO4 is 1.1 × 10⁻⁴ mol/L. The answer is given to two significant figures since the Ksp is given to two significant figures.