Answer:
A. (CH3)3C-I reacts by SN1 mechanism whose rate is independent of nucleophile reactivity.
Explanation:
We must recall that (CH3)3C-I is a tertiary alkyl halide. Tertiary alkyl halides preferentially undergo substitution reaction via SN1 mechanism.
In SN1 mechanism, the rate of reaction depends solely on the concentration of the alkyl halide (unimolecular mechanism) and is independent of the concentration of the nucleophile. As a result of this, both Br^- and Cl^- react at the same rate.
Answer:
D. The relationship between volume and moles
Explanation:
Amedo Avogadro found the relationship between the volume of a gas and the number of molecules contained in the volume.
The law states that "equal volume of all gases at the same temperature and pressure contains the same number of molecules or moles".
Mathematically:
V ∝ n (P,T constant)