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lesya [120]
3 years ago
6

CH4(g)+ 2 O2(g) + CO2(g) + 2 H20 (l)

Chemistry
1 answer:
jasenka [17]3 years ago
4 0

Answer:

<u>∆H° reaction = -890.3 kJ</u>

Explanation:

The given equation is :

CH_{4}(g)+2O_{2}(g)\rightarrow CO_{2}(g)+2H_{2}O(l)

Now ,

O2 is in the standard state so its  ∆H° is zero.

∆H° is calculated by considering the formation of CO2 , H2O and CH4 .

C(s)+H_{2}(g)\rightarrow CO_{2}..........∆H°a = -393.5 kJ

H_{2}+\frac{1}{2}O_{2}\rightarrow H_{2}O(l).....∆H°b = -285.8 kJ

C+2H_{2}\rightarrow CH_{4}(g)..........∆H°c = -74.8 kJ

Multiply equation of water H2O by 2

and reverse the direction of equation of CH4

Hence the sign of ∆H°c = +74.8 kJ becomes +ve.

We are doing this because CH4 is to be in the reactant side not  in the product side.

∆H° reaction = ∆H°a +2(∆H°b) -∆H°c

∆H° reaction = -393.5 - 2(285.8) + 74.8

∆H° reaction = -890.3 kJ

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Explanation:

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Nonamiya [84]

Answer:

1.7 mL

Explanation:

start with formula M1V1=M2V2

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5 0
3 years ago
The molar heat capacity of ethane is represented in the temperature range 298 K to 400 K by the empirical expression Cp,m in J K
BabaBlast [244]

Answer:

-88.66 kJ/mol

Explanation:

The expressions of heat capacity (Cp,m) for C(s) and for H₂(g) are:

C(s):  Cp,m/(J K-1 mol-1) = 16.86 + (4.77T/10³) - (8.54x10⁵/T²)

H₂(g): Cp,m/(J K-1 mol-1) = 27.28 + (3.26T/10³) + (0.50x10⁵/T²)

Cp = A + BT + CT⁻²

For the Kirchoff's Law:

ΔHf = ΔH°f + \int\limits^{T2}_{T1} {DCp(T)} \, dT

Where ΔH°f is the enthalpy at 298 K, T1 is 298 K, T2 is the temperature given (373 K), and DCp is the variation of Cp (products less reactants). ΔH°f  for ethene is -84.68 kJ/mol and the reaction is:

2C(s) + 3H₂(g) → C₂H₆

So, DCp:

dA = A(C₂H₆) - [2xA(C) + 3xA(H₂)] = 14.73 - [2x16.86 + 3x27.28] = -100.83

dB = B(C₂H₆) - [2xB(C) + 3xB(H₂)] = 0.1272 - [2x4.77x10⁻³ + 3x3.26x10⁻³] = 0.10788

dC = C(C₂H₆) - [2xC(C) + 3xC(H₂)] = 0 - (2x(-8.54x10⁵) + 3x0.50x10⁵) = 15.58x10⁵

dCp = -100.83 + 0.10788T + 15.58x10⁵T⁻²

\int\limits^{373}_{298} {-100.83 + 0.10788T + 15.58x10^5T^{-2}} \, dT = -3796.48 J/mol = -3.80 kJ/mol (solved by a graphic calculator)

ΔHf = -84.68 - 3.80

ΔHf = -88.66 kJ/mol

7 0
3 years ago
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