Firstly the limiting reactant should be identified. Limiting reactant is the reactant that is in limited supply, the amount of product formed depends on the moles present of the limiting reactant.
the stoichiometry of x to y = 1:2
1 mole of x reacts with 2 moles of y
if x is the limiting reactant, there are 3 moles of x, then 6 moles of y should react, however there are only 4 moles of y. Therefore y is the limiting reactant and x is in excess.
4 moles of y reacts with 2 moles of x
since there are 3 moles of x initially and only 2 moles are used up, excess amount of x is 1 mol thats in excess.
Answer: The entropy change of the surroundings will be -17.7 J/K mol.
Explanation: The enthalpy of vapourization for 1 mole of acetone is 31.3 kJ/mol
Amount of Acetone given = 10.8 g
Number of moles is calculated by using the formula:

Molar mass of acetone = 58 g/mol
Number of moles = 
If 1 mole of acetone has 32.3 kJ/mol of enthalpy, then
0.1862 moles will have = 
To calculate the entropy change for the system, we use the formula:

Temperature = 56.2°C = (273 + 56.2)K = 329.2K
Putting values in above equation, we get
(Conversion Factor: 1 kJ = 1000J)
At Boiling point, the liquid phase and gaseous phase of acetone are in equilibrium. Hence,


Explanation:
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