Answer:
a) ΔGrxn = 6.7 kJ/mol
b) K = 0.066
c) PO2 = 0.16 atm
Explanation:
a) The reaction is:
M₂O₃ = 2M + 3/2O₂
The expression for Gibbs energy is:
ΔGrxn = ∑Gproducts - ∑Greactants
Where
M₂O₃ = -6.7 kJ/mol
M = 0
O₂ = 0
b) To calculate the constant we have the following expression:
Where
ΔGrxn = 6.7 kJ/mol = 6700 J/mol
T = 298 K
R = 8.314 J/mol K
c) The equilibrium pressure of O₂ over M is:
Answer:
Rate = k . [B]² . [C]
Explanation:
The dependence of the reaction rate on the concentration of the reactants is given by the reaction order of each one, as shown in the rate equation.
![Rate=k.[A]^{x} .[B]^{y} .[C]^{z}](https://tex.z-dn.net/?f=Rate%3Dk.%5BA%5D%5E%7Bx%7D%20.%5BB%5D%5E%7By%7D%20.%5BC%5D%5E%7Bz%7D)
where,
k is the rate constant
x, y, z are the reaction orders.
- <em>The rate of reaction is not affected by changing the concentration of species A.</em> This means that the reaction order for A is x = 0 since when its concentration changes, the rate stays the same.
- <em>Leaving all other factors identical, doubling the concentration of species B increases the rate by a factor of 4.</em> This means that the reaction order for B is y = 2, so when the concentration is doubled, the new rate is 2² = 4 times the initial rate.
- The rate of the reaction is linearly dependent on the concentration of C. This means that the reaction order for C is z = 1, that is, a linear dependence.
All in all, the rate equation is:
Rate = k . [B]² . [C]
Answer:
Distillation is an important commercial process that is used in the purification of a large variety of materials. However, before we begin a discussion of distillation, it would probably be beneficial to define the terms that describe the process and related properties. ... Elevation of the boiling point with an increase in external pressure, while important in cooking and sterilizing food or utensils, is less important in distillation.
Explanation:
Pressure is affected by gravity,height, and density since pressure = density×height×gravity .
