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erma4kov [3.2K]
3 years ago
13

Bugaboo can be oxidised to a carboxylic acid by heating with acidified potassium manganate (VII). Give the name and structural f

ormula of the carboxylic acid.
Chemistry
1 answer:
Novosadov [1.4K]3 years ago
8 0

Answer:

See below.

Explanation:

CH3CH2CH2CH2OH is butanol.

The carboxylic acid formed , butyric acid has the formula:

CH3CH2CH2COOH.

Structural formula:

       H     H    H       O                  

        |       |      |        ||                      

H  -  C  -  C  -  C   -  C  -  OH

       |       |       |    

      H     H     H

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<em><u>The initial entropy is obtained from the initial pressure and temperature with data from A-6 using interpolation:</u></em>

<em><u>s</u></em><em><u>=</u></em><em><u> </u></em><em><u>8</u></em><em><u>.</u></em><em><u>26</u></em><em><u>5</u></em><em><u>2</u></em><em><u> </u></em><em><u>kJ</u></em><em><u>/</u></em><em><u>kgK</u></em>

<em><u>The final temperature is determined from the entropy and the final pressure with data from A-6 using interpolation:</u></em>

<em><u>T₂ = T₁+</u></em><em><u> </u></em><em><u>T₂ - </u></em><em><u>T₁</u></em><em><u>/</u></em><em><u> </u></em><em><u>8</u></em><em><u>₂</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>8</u></em><em><u>₁</u></em><em><u> </u></em><em><u>(</u></em><em><u> </u></em><em><u>s</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>s</u></em><em><u>₁</u></em><em><u>)</u></em>

<em><u>= </u></em><em><u>(</u></em><em><u>400 +</u></em><em><u> </u></em><em><u>500 - 400</u></em><em><u>/</u></em><em><u>8.3271</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>8.0347</u></em><em><u> </u></em><em><u>(8.2652 - 8</u></em><em><u>)</u></em><em><u>)</u></em>

<em><u>= 478.83°C</u></em>

<em><u>The final enthalpy is determined in the same way:</u></em>

<em><u>h₂= h₁</u></em><em><u> </u></em><em><u>+</u></em><em><u> </u></em><em><u>h₂</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>h₁</u></em><em><u>/</u></em><em><u>s</u></em><em><u>₂</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>s</u></em><em><u>₁</u></em><em><u> </u></em><em><u>( s - s₁)</u></em>

<em><u>= (</u></em><em><u> </u></em><em><u>3275.5</u></em><em><u>+</u></em><em><u> </u></em><em><u>3486.6 </u></em><em><u>-</u></em><em><u> </u></em><em><u>3275.5</u></em><em><u>/</u></em><em><u> </u></em><em><u>8.3271</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>8.0347</u></em><em><u>)</u></em><em><u> </u></em><em><u>(8.265</u></em><em><u>)</u></em>

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