Answer:
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Answer:
b. ΔE rxn is a measure of heat
Explanation:
a. ΔHrxn is the heat of reaction. <em>TRUE. </em>ΔHrxn or change in enthalpy of reaction is per definition the change in heat that is involved in a chemical reaction.
b. ΔErxn is a measure of heat. <em>FALSE. </em>Is the change in internal energy of a reaction
c. An exothermic reaction gives heat off heat to the surroundings. <em>TRUE</em>. An exothermic reaction is a chemical reaction that releases heat.
d. Endothermic has a positive ΔH. <em>TRUE. </em>When a process is exothermic ΔH<0 and when the process is endothermic ΔH>0
e. Enthalpy is the sum of a system's internal energy and the product of pressure and volume. <em>TRUE. </em>Under constant pressure and volume the formula is ΔH = ΔE + PV
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Answer:
The three-step synthesis of trans-2-pentene from acetylene is as follows.
<u>Step -1:</u> Formation of higher order terminal alkyne on reaction with sodium acetylides with haloalkanes.
<u>Step -2:</u> Formation terminal alkyne to nonterminal alkynes.
<u>Step -3:</u> Formation of trans-pent - 2-pent-ene by reduction.
Explanation:
Synthesis of trans-pent-2-yne from ethyne takes place is mainly a three step synthesis which involves formation of higher order terminal alkyne on reaction with sodium acetylides with haloalkane. Second step involves the further alkylation of terminal alkynes to higher order nonterminal alkynes and the third step involves the formation of trans-2-ene by dissolving reduction method.
The chemical reaction of each step of chemical reactions is as follows.
( The rapid motion and collisions of molecules ) with the walls of a container causes pressure.
Source; https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Supplemental_Modules_(Physical_and_Theoretical_Chemistry)/Physical_Properties_of_Matter/States_of_Matter/Properties_of_Gases/Gas_Pressure
Answer:
Step 1;
q = w = -0.52571 kJ, ΔS = 0.876 J/K
Step 2
q = 0, w = ΔU = -7.5 kJ, ΔH = -5.00574 kJ
Explanation:
The given parameters are;
= 100 N·m
= 327 K
= 90 N·m
Step 1
For isothermal expansion, we have;
ΔU = ΔH = 0
w = n·R·T·ln(
/
) = 1 × 8.314 × 600.15 × ln(90/100) = -525.71
w ≈<em> -0.52571</em> kJ
At state 1, q = w = -0.52571 kJ
ΔS = -n·R·ln(
/
) = -1 × 8.314 × ln(90/100) ≈ 0.876
ΔS ≈ 0.876 J/K
Step 2
q = 0 for adiabatic process
ΔU = 25×(27 - 327) = -7,500
w = ΔU = <em>-7.5 kJ</em>
ΔH = ΔU + n·R·ΔT
ΔH = -7,500 + 8.3142 × 300 = -5,005.74
ΔH = ΔU = <em>-5.00574 kJ</em>