When burning sodium (Na) in oxygen (O2), you get sodium oxide (Na2O) and/or sodium peroxide (Na2O2). At high pressures, you can additionally get sodium superoxide (NaO2).
4 Na + O2 → 2 Na2O, and then partially 2 Na2O + O2 → 2 Na2O2.
Under normal conditions, approximately 20% of the mixture is Na2O2.