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Temka [501]
3 years ago
13

A reaction has a ΔH value of +120 kJ and a ΔS value of -42 J/K. At which of the following temperatures is the reaction spontaneo

us (meaning ΔG is negative)?
Chemistry
1 answer:
ollegr [7]3 years ago
6 0

Answer:

the reaction is spontaneous at T > 2900 K

Explanation:

  • ΔG = ΔH - TΔS

∴ ΔH = +120 KJ

∴ ΔS = (-42 J/K)*(KJ/1000 J) = -0.042 KJ/K

∴ ΔG < 0 ⇒ the reaction is spontaneous

⇒ at T = 2900 K:

⇒ ΔG = 120 - (2900)(-0.042) = 120 - 121.8 = - 1.8 KJ < 0

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1. Unas de las formas de producir nitrógeno gaseoso (N2) es mediante la oxidación de metilamina (CH3NH2), tal como se muestra en
Maslowich

Answer:

a) 4CH₃NH₂ + 9O₂ ⇄  4CO₂ + 10H₂O + 2N₂    

b) m = 5,043 g

c) % = 69,4 %

Explanation:

a) La ecuación balanceada es la siguiente:

4CH₃NH₂ + 9O₂ ⇄  4CO₂ + 10H₂O + 2N₂              

En el balanceo, se tiene en la relación estequiométrica que 4 moles de metilamina reacciona con 9 moles de oxígeno para producir 4 moles de dióxido de carbono, 10 moles de agua y 2 moles de nitrógeno.  

b) Para determinar la masa de nitrógeno se debe calcular primero el reactivo limitante:

n_{O_{2}} = \frac{m}{M} = \frac{25,6 g}{31,99 g/mol} = 0,800 moles      

n_{CH_{3}NH_{2}} = \frac{4}{9}*0,800 moles = 0,356 moles

De la ecuación anterior se tiene que la cantidad de moles de metilamina necesaria para reaccionar con 0,800 moles de oxígeno es 0,356 moles, y la cantidad de moles iniciales de metilamina es 0,5 moles, por lo tanto el reactivo limitante es el oxígeno.

Ahora, podemos calcular la masa de nitrógeno producida:

n_{N_{2}} = \frac{2}{9}*n_{O_{2}} = \frac{2}{9}*0,8 moles = 0,18 moles

m_{N_{2}} = n_{N_{2}}*M = 0,18 moles*28,014 g/mol = 5,043 g

Por lo tanto, se pueden producir 5,043 g de nitrógeno.

c) El redimiento de la reacción se puede calcular usando la siguiente fórmula:

\% = \frac{R_{r}}{R_{T}}*100

<u>Donde</u>:

R_{r}: es el rendimiento real

R_{T}: es el rendimiento teórico

\% = \frac{3,5}{5,043}*100 = 69,4

Entonces, el procentaje de rendimiento de la reacción es 69,4%.

Espero que te sea de utilidad!        

5 0
3 years ago
A mixture of methane and air is capable of being ignited only if the mole percent of methane is between 5% and 15%. A mixture co
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Answer:

Explanation:

The air 9% mole% methane have an average molecular weight of:

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In the reactor where methane solution and air are mixed:

In = Out

Air balance:

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<em></em>

The air in the product gas is

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43058 mol air×29g/mol <em>1249 kg air</em>

Percent of oxygen is: \frac{289kg}{1249 kg} =<em>0,231 kg O₂/ kg air</em>

<em></em>

I hope it helps!

4 0
3 years ago
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hope this helps ..................

8 0
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