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lozanna [386]
2 years ago
13

What is the maximum number of moles of N-acetyl-p-toluidine can be prepared from 70. milliliters of 0.167 M p-toluidine hydrochl

oride and an excess of acetic anhydride in an acetate buffer? Enter only the number with two significant figures.
Chemistry
1 answer:
Kitty [74]2 years ago
3 0

Answer:

\large \boxed{\text{0.012 mol}}  

Explanation:

We will need a balanced equation with moles, so let's gather all the information in one place.

               CH₃C₆H₄NH₂·HCl + (CH₃CO)₂O ⟶ CH₃C₆H₄NHCOCH₃ + junk

V/mL:                    70.

c/mol·L⁻¹:             0.167

For simplicity in writing , let's call p-toluidine hydrochloride A and N-acetyl-<em>p</em>-toluidine B.

The equation is then

A + Ac₂O ⟶ B + junk

1. Moles of A

\text{Moles of A} = \text{70. mL A}\times \dfrac{\text{0.167 mmol A}}{\text{1 mL A}}= \text{12 mmol A}

2. Moles of B

The molar ratio is 1 mol B:1 mol A

Moles of B = moles of A = 12 mmol = 0.012 mol

\text{You can prepare $\large \boxed{\textbf{0.012 mol}}$ of N-acetyl-p-toluidine. }

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A. 30cm³

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Based on the chemical reaction:

CaCO₃ + 2HCl → CaCl₂ + H₂O + CO₂

<em>1 mol of calcium carbonate reacts with 2 moles of HCl to produce 1 mol of CO₂</em>

<em />

To solve this question we must convert the mass of each reactant to moles. With the moles we can find limiting reactant and the moles of CO₂ produced. Using PV = nRT we can find the volume of the gas:

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50cm³ = 0.0500dm³ * (0.05 mol / dm³) = 2.5x10⁻³ moles

For a complete reaction of 2.5x10⁻³ moles HCl there are necessaries:

2.5x10⁻³ moles HCl * (1mol CaCO₃ / 2mol HCl) = 1.25x10⁻³ moles CaCO₃. As there are 9.991x10⁻³ moles, HCl is limiting reactant.

The moles produced of CO₂ are:

2.5x10⁻³ moles HCl * (1mol CO₂ / 2mol HCl) = 1.25x10⁻³ moles CO₂

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<em>Where P is pressure = 1atm assuming STP</em>

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1.25x10⁻³ moles * 0.082atmL/molK*273.15K / 1atm = V

0.028L = V

28cm³ = V

As 28cm³ ≈ 30cm³

Right option is:

<h3>A. 30cm³</h3>

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