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lozanna [386]
3 years ago
13

What is the maximum number of moles of N-acetyl-p-toluidine can be prepared from 70. milliliters of 0.167 M p-toluidine hydrochl

oride and an excess of acetic anhydride in an acetate buffer? Enter only the number with two significant figures.
Chemistry
1 answer:
Kitty [74]3 years ago
3 0

Answer:

\large \boxed{\text{0.012 mol}}  

Explanation:

We will need a balanced equation with moles, so let's gather all the information in one place.

               CH₃C₆H₄NH₂·HCl + (CH₃CO)₂O ⟶ CH₃C₆H₄NHCOCH₃ + junk

V/mL:                    70.

c/mol·L⁻¹:             0.167

For simplicity in writing , let's call p-toluidine hydrochloride A and N-acetyl-<em>p</em>-toluidine B.

The equation is then

A + Ac₂O ⟶ B + junk

1. Moles of A

\text{Moles of A} = \text{70. mL A}\times \dfrac{\text{0.167 mmol A}}{\text{1 mL A}}= \text{12 mmol A}

2. Moles of B

The molar ratio is 1 mol B:1 mol A

Moles of B = moles of A = 12 mmol = 0.012 mol

\text{You can prepare $\large \boxed{\textbf{0.012 mol}}$ of N-acetyl-p-toluidine. }

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• There are 8 carbons in the longest chain, so it is called an octane.

2) Now, identify the location of the functional group.

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• Identify the location number of the branch by counting the number of carbons in the same direction as when we counted the location number of the functional group. The methyl branch has a location number of 7.

• Adding the name of the branch before the parent chain, we would arrive at 7-methyl-3-octyne as the IUPAC name of the alkyne.

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A) This option is incorrect as there are only 8 carbons in the parent chain. Although there are 9 carbons in total, the 9th carbon is taken care of in '7-methyl'.

B) Location number of the functional group should be as low as possible, so start counting the number of carbons from the left!

C) Since the functional group is an alkyne, the word 'octane' should be 'octyne' instead.

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