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Gnesinka [82]
3 years ago
13

How many grams of barium sulfate are produced if 25.34 mL of 0.113 M BaCl2 completely react given the reaction: BaCl2 (aq) + Na2

SO4(aq) → BaSO4 (s) + 2NaCl (aq)
Chemistry
1 answer:
jeyben [28]3 years ago
4 0

<u>Answer:</u> The amount of barium sulfate produced in the given reaction is 0.667 grams.

<u>Explanation:</u>

To calculate the number of moles from molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}

Molarity of barium chloride = 0.113 M

Volume of barium chloride = 25.34 mL = 0.02534 L   (Conversion factor: 1 L = 1000 mL)

Putting values in above equation, we get:

0.113mol/L=\frac{\text{Moles of barium chloride}}{0.02534L}\\\\\text{Moles of barium chloride}=0.00286mol

For the given chemical reaction:

BaCl_2(aq.)+Na_2SO_4(aq.)\rightarrow BaSO_4(s)+2NaCl(aq.)

By Stoichiometry of the reaction:

1 mole of barium chloride is producing 1 mole of barium sulfate.

So, 0.00286 moles of barium chloride will produce = \frac{1}{1}\times 0.00286mol=0.00286mol of barium sulfate.

Now, to calculate the mass of barium sulfate, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Molar mass of barium sulfate = 233.38 g/mol

Moles of barium sulfate = 0.00286 moles

Putting values in above equation, we get:

0.00286mol=\frac{\text{Mass of barium sulfate}}{233.38g/mol}\\\\\text{Mass of barium sulfate}=0.667g

Hence, the amount of barium sulfate produced in the given reaction is 0.667 grams

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Calculate the standard entropy change for the following reactions at 25°C.
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Answer:

(a) ΔSº = 216.10 J/K

(b) ΔSº = - 56.4 J/K

(c) ΔSº = 273.8 J/K

Explanation:

We know the standard entropy change for a given reaction is given by the sum of the entropies of the products minus the entropies of reactants.

First we need to find in an appropiate reference table the standard  molar entropies entropies, and then do the calculations.

(a)        C2H5OH(l)          +        3 O2(g)         ⇒        2 CO2(g)     +    3 H2O(g)

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(b)         CS2(l)               +         3 O2(g)               ⇒      CO2(g)      +      2 SO2(g)

Sº          151.0                              205.2                         213.8                 248.2

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ΔSº  = [ 213.8 + 2(248.2) ] - [ 151.0 + 3(205.2) ] J/K = - 56.4 J/K

(c)        2 C6H6(l)           +        15 O2(g)                     12 CO2(g)     +     6 H2O(g)

Sº           173.3                           205.2                           213.8                    188.8

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ΔSº  = [ 12(213.8) + 6(188.8) ] - [ 2(173.3) + 15( 205.2) ] = 273.8 J/K

Whenever possible we should always verify if our answer makes sense. Note that the signs for the entropy change agree with the change in mol gas. For example in reaction (b) we are going from 4  total mol gas reactants to 3, so the entropy change will be negative.

Note we need to multiply the entropies of each substance by  its coefficient in the balanced chemical equation.

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