<u>Answer:</u> The volume of acid should be less than 100 mL for a solution to have acidic pH
<u>Explanation:</u>
To calculate the volume of acid needed to neutralize, we use the equation given by neutralization reaction:

where,
are the n-factor, molarity and volume of acid which is HCl
are the n-factor, molarity and volume of base which is NaOH
We are given:

Putting values in above equation, we get:

For a solution to be acidic in nature, the pH should be less than the volume of acid needed to neutralize.
Hence, the volume of acid should be less than 100 mL for a solution to have acidic pH