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Answer:
CH3CH2NH3+/CH3CH2NH2 would have the largest pKa
Explanation:
To answer this question we must know Kb of CH3CH2NH2 is 5.6x10⁻⁴, and for C6H5NH2 is 4.0x10⁻¹⁰. And the CH3CH2NH3+ and C6H5NH3+ are related with these substances because are their conjugate base. That means:
pKa of CH3CH2NH3+ = CH3CH2NH2; C6H5NH3+ = C6H5NH2
Also, Kw / Kb = Ka
Thus:
pKa of CH3CH2NH3+/CH3CH2NH2 is:
Kw / kb = Ka = 1.79x10⁻¹¹
-log Ka = pKa
pKa = 10.75
pKa of C6H5NH3+/ C6H5NH2 is:
Kw / kb = Ka = 2.5x10⁻⁵
-log Ka = pKa
pKa = 4.6
That means CH3CH2NH3+/CH3CH2NH2 would have the largest pKa
Methane, CH4, would have the lowest boiling point among the three since it has the lowest number of carbon and has no functional groups. Methanol would have the highest boiling point since it has a functional group which contains hydrogen bonding which much stronger than the one in CH3Cl. Hope this helps.<span />
Hello there!
The statement that Acid strength in a series of H-A molecules increases with increasing size of A is True.
When only the size is involved, increasing the size will increase the Acid strength because as size increases, the H-A bond will become weaker as the atoms will be farther apart. Acid strength is related to the ability to release H⁺ ions and a weaker H-A bond will release H⁺ more easily.
Have a nice day!
Answer:
BCI3 is a non polar compound because there is no neutral in it
