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ozzi
3 years ago
12

Scoring Scheme: 3-3-2-1 Part III. For each trial, enter the amount of heat gained by the chemical system of ammonium nitrate, qr

xn. The specific heat of water is 4.184 J/goC. Report your answer using 4 digits. Trial
Chemistry
1 answer:
WITCHER [35]3 years ago
7 0

Question:

The information given is:

Trial #      Tiwater     T f           ΔT        Masswater  (m)

       #1:     21.2         10.8        10.8       24.990

       #2:    20.8        9.50       9.5         25.000

       #3:    20.9        9.20       9.2         25.010

Answer:

The heat of the reaction is -5985 J

Explanation:

The heat absorbed by the water is given by

ΔQ = m·c·ΔT  

From which

∑ (ΔT·m)/3 = 278.34 kg·°C

ΔQ = c×∑ (ΔT·m)/3 = 4.184 J/g·°C×278.34 kg·°C = 1164.565 J

ΔQ Calorimter = Specific heat capacity of calorimeter, c_{calorimeter} × ΔT_{average}

Where the c_{calorimeter} = 443 J/°C for example, we have

ΔQ Calorimter = 443×11.133 = 4820.733 J

From which the heat of reaction is then

\Delta Q_{reaction} = -(\Delta Q_{water} + \Delta Q_{calorimter})

\Delta Q_{reaction} = -5985.298 \, J

Using 4 digits, we get

\Delta Q_{reaction} \approx  -5985 \, J.

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2. Calculate the mass of 3.47x1023 gold atoms.
lapo4ka [179]

3.47 x 10^{23} atoms of gold have mass of 113.44 grams.

Explanation:

Data given:

number of atoms of gold = 3.47 x 10^{23}

mass of the gold in given number of atoms = ?

atomic mass of gold =196.96 grams/mole

Avagadro's number = 6.022 X 10^{23}

from the relation,

1 mole of element contains 6.022 x 10^{23} atoms.

so no of moles of gold given = \frac{3.47 X 10^{23}  }{6.022 X 10^{23} }

0.57 moles of gold.

from the relation:

number of moles = \frac{mass}{atomic mass of 1 mole}

rearranging the equation,

mass = number of moles x atomic mass

mass = 0.57 x 196.96

mass = 113.44 grams

thus, 3.47 x 10^{23} atoms of gold have mass of 113.44 grams

3 0
3 years ago
Rank these acids according to their expected pKa values.
givi [52]

Answer:

According to their expected pKa values, the order of those acids should be:

1- Cl2CHCOOH is the strongest acid and the lowest pKa.

2- ClCH2COOH is a strong acid, but no more than the first. Medium pKa value.

3- ClCH2CH2COOH is a strong acid, but no more than the two previous acids. High pKa value.

4- CH3CH2COOH  is the weakest acid, so the highest pKa value.

Explanation:

The pKa values are the negative logarithm of dissociation constant. It represents the relative strengths of the acids. Stronger acids show smaller pKa values and weak acids present larger pKa value. The stronger the acid, the weaker it's the conjugate base. The larger the pKa of the conjugate base, the stronger the acid. The strength of an acid is inversely related to the strength of its conjugate.

Conjugate bases are the substance that has one less proton than the parent acid. The conjugate base of the acid presented in the problem are:

ClCH2COOH -> ClCH2COO-  + H+

ClCH2CH2COOH -> ClCH2CH2COO- + H+

CH3CH2COOH -> CH3CH2COO- + H+

Cl2CHCOOH -> Cl2CHCOO - + H+

Cl2CHCOOH. The negative charge presented on its conjugate base is by resonance and inductive effect. This is the strongest acid.

ClCH2COOH. A negative charge is stabilized by resonance and electron-withdrawing but only one atom is present. So this acid is less strong than the first one.

ClCH2CH2COOH. The negative charge is stabilized by resonance and electron-withdrawing atom but the effect is less compared to the two acids showed previously.

CH3CH2COOH. The negative charge is stabilized by resonance and destabilized due to CH3 group. This is the weakest acid among the problem.

Stronger acids have smaller pKa values and weak acids have larger pKa values. Due to the information present in this problem, Cl2CHCOOH is the strongest acid and the lowest pKa. CH3CH2COOH is the weakest acid, so the highest pKa value.

Finally, we can conclude that according to their expected pKa values, the order of those acids should be:

1- Cl2CHCOOH is the strongest acid and the lowest pKa.

2- ClCH2COOH is a strong acid, but no more than the first. Medium pKa value.

3- ClCH2CH2COOH is a strong acid, but no more than the two previous acids. High pKa value.

4- CH3CH2COOH  is the weakest acid, so the highest pKa value.

3 0
3 years ago
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olga nikolaevna [1]

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Chlorofluorocarbons are very harmful to the environment when released into the atmosphere. They damage the ozone layer and therefore allow more UV rays from sunlight to reach the earth’s surface. They also have a  greenhouse effect causing the earth’s atmosphere to warm up. This ultimately leads to global warming and climate change.

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6 0
3 years ago
The hydronium ion concentration in a solution at ph 10 has what relationship to the hydronium ion concentration in a solution at
fgiga [73]
<span>Based on your information 1000 times greater than pH 13 is the best I can come up </span>with. 
8 0
3 years ago
Consider the reaction between iron (III) oxide, Fe2O3 and carbon monoxide, CO. Fe2O3 + 3CO --&gt; 2Fe + 3CO2 In the process, 213
s344n2d4d5 [400]
To calculate the mass of Fe formed in a) we get first the limiting reactant between Fe2O3 and CO. Given the masses, the ratio of Fe2O3 is 1.33 while that of CO is 1.67. Hence the limiting reagent is Fe2O3. The mass of Fe formed is 148.98 grams. In b, the needed CO is only 112.04 grams. Hence, the excess is 27. 96 grams. 
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3 years ago
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