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ozzi
3 years ago
12

Scoring Scheme: 3-3-2-1 Part III. For each trial, enter the amount of heat gained by the chemical system of ammonium nitrate, qr

xn. The specific heat of water is 4.184 J/goC. Report your answer using 4 digits. Trial
Chemistry
1 answer:
WITCHER [35]3 years ago
7 0

Question:

The information given is:

Trial #      Tiwater     T f           ΔT        Masswater  (m)

       #1:     21.2         10.8        10.8       24.990

       #2:    20.8        9.50       9.5         25.000

       #3:    20.9        9.20       9.2         25.010

Answer:

The heat of the reaction is -5985 J

Explanation:

The heat absorbed by the water is given by

ΔQ = m·c·ΔT  

From which

∑ (ΔT·m)/3 = 278.34 kg·°C

ΔQ = c×∑ (ΔT·m)/3 = 4.184 J/g·°C×278.34 kg·°C = 1164.565 J

ΔQ Calorimter = Specific heat capacity of calorimeter, c_{calorimeter} × ΔT_{average}

Where the c_{calorimeter} = 443 J/°C for example, we have

ΔQ Calorimter = 443×11.133 = 4820.733 J

From which the heat of reaction is then

\Delta Q_{reaction} = -(\Delta Q_{water} + \Delta Q_{calorimter})

\Delta Q_{reaction} = -5985.298 \, J

Using 4 digits, we get

\Delta Q_{reaction} \approx  -5985 \, J.

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Examine the reactants of the incomplete double-displacement reaction. 2NaCl + H2SO4 → __________. Which of the answer choices co
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He rate constant of a reaction is 4.55 × 10−5 l/mol·s at 195°c and 8.75 × 10−3 l/mol·s at 258°c. what is the activation energy o
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Answer : The activation energy of the reaction is, 17.285\times 10^4kJ/mole

Solution :  

The relation between the rate constant the activation energy is,  

\log \frac{K_2}{K_1}=\frac{Ea}{2.303\times R}\times [\frac{1}{T_1}-\frac{1}{T_2}]

where,

K_1 = initial rate constant = 4.55\times 10^{-5}L/mole\text{ s}

K_2 = final rate constant = 8.75\times 10^{-3}L/mole\text{ s}

T_1 = initial temperature = 195^oC=273+195=468K

T_2 = final temperature = 258^oC=273+258=531K

R = gas constant = 8.314 kJ/moleK

Ea = activation energy

Now put all the given values in the above formula, we get the activation energy.

\log \frac{8.75\times 10^{-3}L/mole\text{ s}}{4.55\times 10^{-5}L/mole\text{ s}}=\frac{Ea}{2.303\times (8.314kJ/moleK)}\times [\frac{1}{468K}-\frac{1}{531K}]

Ea=17.285\times 10^4kJ/mole

Therefore, the activation energy of the reaction is, 17.285\times 10^4kJ/mole

8 0
3 years ago
Read 2 more answers
A 0.708 g sample of a metal, M, reacts completely with sulfuric acid according to the reaction M ( s ) + H 2 SO 4 ( aq ) ⟶ MSO 4
ollegr [7]

Answer:

The metal has a molar mass of 65.37 g/mol

Explanation:

Step 1: Data given

Mass of the metal = 0.708 grams

Volume of hydrogen = 275 mL = 0.275 L

Atmospheric pressure = 1.0079 bar = 0.9947 atm

Temperature = 25°C

Vapor pressure of water at 25 °C = 0.03167 bar = 0.03126 atm

Step 2: The balanced equation

M(s) + H2SO4(aq) ⟶ MSO4 (aq) + H2(g)

Step 3: Calculate pH2

Atmospheric pressure = vapor pressure of water + pressure of H2

0.9947 atm = 0.03126 atm + pressure of H2

Pressure of H2 = 0.9947 - 0.03126

Pressure of H2 = 0.96344 atm

Step 4: Calculate moles of H2

p*V=n*R*T

⇒ with p = The pressure of H2 = 0.96344 atm

⇒ with V = the volume of H2 = 0.275 L

⇒ with n = the number of moles H2 = TO BE DETERMINED

⇒ with R = the gas constant = 0.08206 L*atm/K*mol

⇒ with T = the temperature = 25°C = 298 Kelvin

n = (p*V)/(R*T)

n = (0.96344 * 0.275)/(0.08206*298)

n = 0.01083 moles

Step 5: Calculate moles of M

For 1 mole of H2 produced, we need 1 mole M

For 0.0108 moles of H2 we need 0.01083 moles of M

Step 6: Calculate molar mass of M

Molar mass M = Mass M / moles M

Molar mass M = 0.708 grams / 0.01083 moles

Molar mass M = 65.37 g/mol

The metal has a molar mass of 65.37 g/mol

5 0
3 years ago
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