Answer:
The final temperature of the solution is 44.8 °C
Explanation:
assuming no heat loss to the surroundings, all the heat of solution (due to the dissolving process) is absorbed by the same solution and therefore:
Q dis + Q sol = 0
Using tables , can be found that the heat of solution of CaCl2 at 25°C (≈24.7 °C) is q dis= -83.3 KJ/mol . And the molecular weight is
M = 1*40 g/mol + 2* 35.45 g/mol = 110.9 g/mol
Q dis = q dis * n = q dis * m/M = -83.3 KJ/mol * 13.1 g/110.9 gr/mol = -9.84 KJ
Qdis= -9.84 KJ
Also Qsol = ms * Cs * (T - Ti)
therefore
ms * Cs * (T - Ti) + Qdis = 0
T= Ti - Qdis * (ms * Cs )^-1 =24.7 °C - (-9.84 KJ/mol)/[(104 g + 13.1 g)* 4.18 J/g°C] *1000 J/KJ
T= 44.8 °C
When the pressure is increased, the equilibrium will shift to the left to offset the pressure increase. Equilibrium shifting to the left side is favored because the left side has fewer moles of gas than the number of moles of gas on the right-hand side and because it exerts less pressure. Therefore, the answer is there will be a shift toward the reactants.
3501.75
is the answer
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Answer:
Explanation:
Solubility of many solid in a solvent increases with increase in temperature. Increase in temperature increases kinetic energy of the solute, increasing collision and weakens the intermolecular force within the solute. This makes the solute dissolve faster in their solvents.
During recrystallization, more solutes are added to the solvent at higher temperature so that a supersaturated solution is produced on cooling. As the solution cools the over saturated solute begins to precipitate out of the solution.
Recrystallization is a form of purification if solid, as the crystalline solids continue to precipitate it reject impurities are comes out as a purer solid
KClO3 (aq) will have greater molar entropy than KClO3 (s) because molar entropy increases with increase in temperature.
As the temperature rises, the standard molar entropy of any substance rises. Entropy and a Single Substance's Temperature ” Entropy increases significantly when a solid turns into a liquid and when a liquid turns into a gas. The entropy of the liquid is lower than that of the gas. As a result, entropy rises in reactions that produce gaseous byproducts from solid or liquid reactants. When solid reactants produce liquid products, entropy also rises.
Learn more about Molar entropy here-
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