Answer:
a) Ql=33120000 kJ
b) COP = 5.6
c) COPreversible= 29.3
Explanation:
a) of the attached figure we have:
HP is heat pump, W is the work supplied, Th is the higher temperature, Tl is the low temperature, Ql is heat supplied and Qh is the heat rejected. The worj is:
W=Qh-Ql
Ql=Qh-W
where W=2000 kWh
Qh=120000 kJ/h

b) The coefficient of performance is:

c) The coefficient of performance of a reversible heat pump is:

Th=20+273=293 K
Tl=10+273=283K
Replacing:

Answer:
a)W=12.62 kJ/mol
b)W=12.59 kJ/mol
Explanation:
At T = 100 °C the second and third virial coefficients are
B = -242.5 cm^3 mol^-1
C = 25200 cm^6 mo1^-2
Now according isothermal work of one mole methyl gas is
W=-
a=
b=
from virial equation

And

a=
b=
Now calculate V1 and V2 at given condition

Substitute given values
= 1 x 10^5 , T = 373.15 and given values of coefficients we get

Solve for V1 by iterative or alternative cubic equation solver we get

Similarly solve for state 2 at P2 = 50 bar we get

Now

a=241.33
b=30780
After performing integration we get work done on the system is
W=12.62 kJ/mol
(b) for Z = 1 + B' P +C' P^2 = PV/RT by performing differential we get
dV=RT(-1/p^2+0+C')dP
Hence work done on the system is

a=
b=
by substituting given limit and P = 1 bar , P2 = 50 bar and T = 373 K we get work
W=12.59 kJ/mol
The work by differ between a and b because the conversion of constant of virial coefficients are valid only for infinite series
Answer:
A) Linear Equation -
Linear equation has only one independent variable and when the linear equation plotted on a graph it forms a straight line. It is made up of two expressions equal to each other in a equation. Linear equation graph fits the Y= mx+a ( m=slope).
B) Laplace's equation is linear as it is a second order partial differential equation. So if we put dependent variable in differential equation it always show result in linear.
Answer:
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