Answer:
The correct answer is due to the difference in pressure inside and outside the bottle.
Explanation:
Liquids have melting and boiling points that depend on pressure and temperature. The pressure inside the bottle is higher than the pressure outside. This causes the melting point to drop, making the liquid freeze at a lower temperature than if it were at atmospheric pressure, and therefore has a lower temperature than it would freeze at atmospheric pressure. When the bottle is uncovered, the liquid becomes an atmospheric pressure, and due to the temperature acquired when the bottle was closed the liquid freezes.
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The first one is exothermic because energy is a reactant, the second formula is endothermic
        
             
        
        
        
1) divide each percentage by the relative atomic mass of the element
2) divide all results by the smallest number 
3)multiply by a whole number to get the simplest whole number ratio (if necessary) 
that is to say: 
Na                                   S                            O 
32.37÷23                 22.58÷32                45.05÷16
= 1.407                       = 0.7056               = 2.816        (to 4 significant figures)
the smallest number here is 0.7056 so:
1.407÷0.7056        0.7056÷0.7056       2.816÷0.7056
=1.99 approx.2                   = 1                   3.99 approx. 4
here there is no need to carry out step 3 as ratio obtained is already a simplest whole number  ratio 
so empirical formula is: Na₂SO₄
 
        
             
        
        
        
The energy of the wave does not move through anything