Answer:
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Explanation:
The lowering of the freezing point of a solvent is a colligative property ruled by the formula:
Where:
- ΔTf is the lowering of the freezing point
- Kf is the molal freezing constant of the solvent: 1.86 °C/m
- m is the molality of the solution
- i is the van't Hoff factor: the number of particles (ions) per unit of ionic compound.
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<u>a) molality, m</u>
- m = number of moles of solute/ kg of solvent
- number of moles of CaI₂ = mass in grams/ molar mass
- number of moles of CaI₂ = 25.00g / 293.887 g/mol = 0.0850667mol
- m = 0.0850667mol/1.25 kg = 0.068053m
<u>b) i</u>
- Each unit of CaI₂, ideally, dissociates into 1 Ca⁺ ion and 2 I⁻ ions. Thus, i = 1 + 2 = 3
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<u>c) Freezing point lowering</u>
- ΔTf = 1.86 °C/m × 0.068053m × 3 = 0.3797ºC ≈ 0.380ºC
<h2>I have problems to upload the full answer in here, so I attach a pdf file with the whole answer.</h2>
The heat required to vaporize 43.9 g of acetone at its boiling point is calculated as below
the heat of vaporization of acetone at its boiling point is 29.1 kj/mole
find the moles of acetone = mass/molar mass
= 43.9g /58 g/mol =0.757 moles
heat (Q) = moles x heat of vaporization
= 29.1 kj/mole x 0.757 moles = 22.03 kj
To determine which order of the reaction it is, first we need to calculate the rate of change of moles.
the data is as follows
time 0 40 80 120 160
moles 0.100 0.067 0.045 0.030 0.020
Q1)
for the first 40 s change of moles ;
= -d[A] / t
= - (0.067-0.100)/40s
= 8.25 x 10⁻⁴ mol/s
for the next 40 s
= -(0.045-0.067)/40
= 5.5 x 10⁻⁴ mol/s
the 40 s after that
= -(0.030-0.045)/40 s
= 3.75 x 10⁻⁴ mol/s
k - rate constant
and A is the only reactant that affects the rate of the reaction
rate = k [A]ᵇ
8.25 × 10⁻⁴ mol/s = k [0.100 mol]ᵇ ----1
5.5 x 10⁻⁴ mol/s = k [0.067 mol]ᵇ -----2
divide the 2nd equation by the 1st equation
1.5 = [1.49]ᵇ
b is almost equal to 1
Therefore this is a first order reaction
Q2)
to find out the rate constant(k), we have to first state the equation for a first order reaction.
rate = k[A]ᵇ
As A is the only reactant thats considered for the rate equation.
Since this is a first order reaction,
b = 1
therefore the reaction is
rate = k[A]
substituting the values,
8.25 x 10⁻⁴ mol/s = k [0.100 mol]
k = 8.25 x 10⁻⁴ mol/s /0.100mol
= 8.25 x 10⁻³ s⁻¹
CO2, C2H2, BeF2, XeF2, etc all these molecules have linear geometry.
A compound is a substance that consists of 2 or more elements chemically combined in a fixed proportion.
Compounds can be broken down ijt0 simple substances by chemical means but, elements cannot.
