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2 years ago

In the addition of hbr to 1-butyne the electrophile in the first step of the mechanism is

1 answer:

7 0

Answer:
<span>In the addition of hbr to 1-butyne the electrophile in the first step of the mechanism is <u>Hydrogen atom of HBr</u>.

Explanation:
In this reaction first of all HBr approaches the triple bond. A Pi Complex (weak inter-molecular interactions) is formed between the two molecules. And the triple bond attacks the partial positive hydrogen atom creating a negative charge on Bromine along with positive charge on itself (Sigma Complex). In second step the negative Bromide attacks the positive carbon of Butyne.</span>

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At a certain temperature the vapor pressure of pure benzene is measured to be . Suppose a solution is prepared by mixing of benz

Marianna [84]

Answer:

P(C₆H₆) = 0.2961 atm

Explanation:

I found an exercise pretty similar to this, so i'm gonna use the data of this exercise to show you how to do it, and then, replace your data in the procedure so you can have an accurate result:

<em>"At a certain temperature the vapor pressure of pure benzene (C6H6) is measured to be 0.63 atm. Suppose a solution is prepared by mixing 79.2 g of benzene and 115. g of heptane (C7H16) Calculate the partial pressure of benzene vapor above this solution. Round your answer to 2 significant digits. Note for advanced students: you may assume the solution is ideal".</em>

<em />

Now, according to the data, we want partial pressure of benzene, so we need to use Raoul's law which is:

P = Xₐ * P° (1)

Where:

P: Partial pressure

Xₐ: molar fraction

P°: Vapour pressure

We only have the vapour pressure of benzene in the mixture. We need to determine the molar fraction first. To do this, we need the moles of each compound in the mixture.

To get the moles: n = m / MM

To get the molar mass of benzene (C₆H₆) and heptane (C₇H₁₆), we need the atomic weights of Carbon and hydrogen, which are 12 g/mol and 1 g/mol:

MM(C₆H₆) = (12*6) + (6*1) = 78 g/mol

MM(C₇H₁₆) = (7*12) + (16*1) = 100 g/mol

Let's determine the moles of each compound:

moles (C₆H₆) = 79.2 / 78 = 1.02 moles

moles (C₇H₁₆) = 115 / 100 = 1.15 moles

moles in solution = 1.02 + 1.15 = 2.17 moles

To get the molar fractions, we use the following expression:

Xₐ = moles(C₆H₆) / moles in solution

Xₐ = 1.02 / 2.17 = 0.47

Finally, the partial pressure is:

P(C₆H₆) = 0.47 * 0.63

Hope this helps

7 0

2 years ago

What is the pH of a 0.28 M solution of ascorbic acid

Nady [450]

Hey there!

Values Ka1 and Ka2 :

Ka1 => 8.0*10⁻⁵

Ka2 => 1.6*10⁻¹²

H2A + H2O -------> H3O⁺ + HA⁻

Ka2 is very less so I am not considering that dissociation.

Now Ka = 8.0*10⁻⁵ = [H3O⁺] [HA⁻] / [H2A]

lets concentration of H3O⁺ = X then above equation will be

8.0*10−5 = [x] [x] / [0.28 -x

8.0*10−5 = x² / [0.28 -x ]

x² + 8.0*10⁻⁵x - 2.24 * 10⁻⁵

solve the quardratic equation

X =0.004693 M

pH = -log[H⁺]

pH = - log [ 0.004693 ]

pH = 2.3285

Hope that helps!

3 0

2 years ago

Plzzzzz help me to solve this question.

aleksklad [387]

Answer:

Explanation:

A1. Chemical indicator, any substance that gives a visible sign, usually by a colour change, of the presence or absence of a threshold concentration of a chemical species, such as an acid or an alkali in a solution. An example is the substance called methyl yellow, which imparts a yellow colour to an alkaline solution.

A2. The reaction of an acid with a base is called a neutralization reaction. The products of this reaction are a salt and water. ... For example, the reaction of hydrochloric acid, HCl, with sodium hydroxide, NaOH, solutions produces a solution of sodium chloride, NaCl, and some additional water molecules

A3. Methyl orange has the property to color alkaline and neutral water yellow. If the water becomes acidic, it turns red immediately.

3 0

2 years ago

Solid sodium hydrogen carbonate, NaHCO3, decomposes on heating according to the equation:

tekilochka [14]

Answer:

See explanation

Explanation:

First, let's write the balanced equation again:

2 NaHCO3(s) <-> Na2CO3(s) + H2O(g) + CO2(g)

Now, we know that the total pressure was 7.76 atm. This total pressure, is the sum of the pressure of water and CO2 like this:

Ptotal = Pwat + PCO2 (1)

This is the dalton's law for partial pressures.

The pressure can be also be relationed with the moles

Ratio of mole = Ratio of pressure

so, taking this in consideration we can say the following:

Pwater/PCO2 = moles water / moles CO2

As the only components exerting pressure are CO2 and Water (Because they are in gas phase), the total pressure can be splitted between the two of them so:

Pwater = Ptotal/2

Pwater = 7.76 / 2 = 3.88 atm

With this pressure, and using the ideal gas equation, we can know the moles of water:

PV = nRT

n = PV/RT using R = 0.082 L atm / K mol

n = 3.88 * 5 / 0.082 * (160+273)

n = 0.546 moles of water

b) now that we have the moles of water, we can actually know the moles that reacted originally from the sodium carbonate by stechiometry.

2NaHCO3(s) <-> Na2CO3(s) + H2O(g) + CO2(g) MMCO2 = 84 g/mol

the moles of NaHCO3 initially:

n = 100 / 84

n = 1.19 moles

so, If 1.19 moles of NaHCO3 reacted, and only produces 0.546 moles of water and CO2, then, the remaining moles of NaHCO3 is:

remaining moles = 1.19 - 0.546 = 0.644 moles

therefore the mass remaining:

mCO2 = 0.644 * 84

mCO2 = 54.096 g

c) As it was stated before, only the gaseous components are involved in the pressure, thus, in the kp expression which is:

Kp = Pwater * PCO2

Kp = 3.88 * 3.88

Kp = 15.0544

d) As the total pressure is 7.76 atm and the fact that NaHCO3 is solid, this component is not exerting any pressure in the reaction, as seen in the Kp expression, so it won't matter that if we raise a little the quantity of the reactant, it still has some remaining.

3 0

3 years ago

Sh, are you fine, oh oh oh oh oh oh oh oh oh oh no on n, nt ag, do not hesitate, wa ag, do not hesitate to contact me

lidiya [134]

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6 0

3 years ago