Answer:
The most reactive compound is:<u> Phenol </u> because the<u> electron donating</u> character of the <u>alcohol group</u> increases the rate of the reaction.
The least reactive compound is <u>nitrobenzene</u>
because the <u>electron withdrawing</u> character of the<u> nitro group</u> decreases the rate of the reaction.
Explanation:
- PHENOL-: Any of a group of organic compounds with a hydroxyl (OH) group bound to a carbon atom in an aromatic ring is known as phenol. The word phenol is also the basic name for its simplest member, monohydroxybenzene (C6H5OH), also known as benzenol or carbolic acid, in addition to being the common name for the entire family.
- ELECTRON DONATING CHARACTER-: Via the carbon atom it is bound to, an electron donating group (EDG) has the net effect of increasing electron density in a molecule. EDGs alter a molecule's reactivity by increasing electron density on neighboring carbon atoms: EDGs make nucleophiles stronger.
- ALCOHOL GROUP-:Each of a class of organic compounds that have one or more hydroxyl (OH) groups bound to an alkyl group's carbon atom (hydrocarbon chain)is called Alcohol. Alcohols are organic compounds of water
in which one of the hydrogen atoms has been substituted by an alkyl group, which in organic structures is usually expressed by R. - NITROBENZENE-:The organic compound nitrobenzene has the chemical formula
. It's a pale yellow oil that's insoluble in water and smells like almonds. Greenish-yellow crystals form when it freezes. It is made on a wide scale as a precursor to aniline from benzene. It is sometimes used as a solvent in the laboratory, especially for electrophilic reagents. - ELECTRON WITHDRAWING GROUP-: An electron withdrawing group (EWG) is a type of group that reduces electron density in a molecule by bonding to a carbon atom. EWGs alter a molecule's reactivity by reducing electron density on neighboring carbon atoms.
- NITRO GROUP-: The nitro group is one of the most widely used explosophores (functional groups that combine to form a compound explosive). In addition, the nitro group is a heavy electron-withdrawing group. CH bonds alpha (adjacent) to the nitro group may be acidic due to this property.
Answer:
The new volume of the gas is 21 L.
Explanation:
Volume of a gas is inversely proportional to its pressure at constant temperature such that,
or
We have,
It is required to find V₂. Using above law or Boyle's law such that :
So, the new volume of the gas is 21 L.
Answer:
a. CH3NH2(aq) + H⁺ → CH3NH3⁺
Explanation:
The mixture of a weak base as CH3NH2 with its conjugate acid CH3NH3Cl produce a buffer. As the weak acid is in equilibrium with water, the mixture of the weak base and its conjugate base produce that the acid or base released react avoiding the change in pH.
For example, when a strong acid as HNO3 reacts, the weak base will react producing the conjugate base, that is:
CH3NH2(aq) + H⁺ → CH3NH3⁺
Right answer is:
<h3>a. CH3NH2(aq) + H⁺ → CH3NH3⁺</h3>
Because displacement of water is the convenient way to obtain gas.
The freezing point of a 1.324 m solution, prepared by dissolving biphenyl into naphthalene, is 71.12 ° C.
A solution is prepared by dissolving biphenyl into naphthalene. We can calculate the freezing point depression (ΔT) for naphthalene using the following expression.
where,
- i: van 't Hoff factor (1 for non-electrolytes)
- Kf: cryoscopic constant
- m: molality
The normal freezing point of naphthalene is 80.26 °C. The freezing point of the solution is:
The freezing point of a 1.324 m solution, prepared by dissolving biphenyl into naphthalene, is 71.12 ° C.
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