It can be easily judged that only the first reaction is an acid base reaction among the three given in the question. So, we can avoid the other two reactions given in the question. Now let us focus and write down the balanced chemical equation of <span>P-Toluidine + HCl.
</span><span>C7H9N + HCl = C7H10N (+) + Cl (-)
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I hope the answer has come to your help.
2. <span>(Note that sulfur is 2 columns from the right-hand end of the periodic table)</span>
Answer : Option D) The pH of the solution is 8.0.
Explanation : pOH of a solution is a measure of hydroxide ion 
concentration in a particular solution. It gives the measure of alkalinity of a solution. Normally, aqueous solutions at 25°C have pOH which is less than 7 are usually alkaline, when pOH is found to be greater than 7 then they are acidic and when pOH will be equal to 7 then it is neutral.
pH + pOH = 14, this relationship is used to find pH of any unknown solution with given pOH value,
Here, we known pOH is 6.0, so we get,
pH = 14 - 6 = 8.0;
Hence, the pH will be 8.0.
