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Romashka [77]
3 years ago
13

The reaction between ethylene and hydrogen bromide to form ethyl bromide is carried out in a continuous reactor. The product str

eam is analyzed and found to contain 56.7 mol% C2H5Br and 10.3 mol% HBr. The feed to the reactor conains only ethylene and hydrogen bromide. Calculate the fractional conversion of the limiting reactant and the percentage by which the other reactant is in excess. If the molar flow rate of the feed stream is 265 mol/s, what is the extent of reaction
Chemistry
1 answer:
kirill [66]3 years ago
4 0

Answer:

Extent of reaction = 95.9 mol.

Fractional conversion of the limiting reactant = 0.846.

Percentage by which the other reactant is in excess = 25.2 %.

Explanation:

Hello.

In this case, for the undergoing chemical reaction:

CH_2=CH_2+HBr\rightarrow CH_3-CH_2Br

We can write the mole balance per species also including the extent of the reaction:

CH_2=CH_2:A\\\\HBr: B\\\\CH_3-CH_2-Br:C

x_AP=z_AF-\epsilon \\\\x_BP=z_BF-\epsilon \\\\x_CP=\epsilon

Considering that P is the flow of the outlet product. In such a way, writing the data we know, we can write:

0.33P=z_A*265-\epsilon \\\\0.103P=z_B*265-\epsilon \\\\0.567P=\epsilon

Whereas we can replace the C2H5Br mole balance in the others mole balances:

0.33P=z_A*265-0.567P \\\\0.103P=z_B*265-0.567P\\\\\\z_A*265-0.897P=0\\\\z_B*265-0.67P=0

By knowing that z_B=1-z_A, we can write:

z_A*265-0.897P=0\\\\(1-z_A)*265-0.67P=0\\\\\\z_A*265-0.897P=0\\\\-z_A*265-0.67P=-265

Thus, solving for P and z_A, we obtain:

z_A=0.572\\\\P=169.11mol

It means that the extent of the reaction is:

\epsilon=0.567P=0.567*169.11mol\\\\\epsilon=95.9mol

For the limiting reactant, due to the 1:1 mole ratio between the reactants, it is the one having the smallest flow rate:

F_A=0.572*265mol=151.58mol\\\\F_B=265mol-151.58mol=113.42mol

It means that the limiting reactant is B which is HBr, whose fractional conversion is:

X_B=1-\frac{0.103*169.11}{113.42mol}\\ \\X_B=0.846

Finally, the percentage by which the other reactant is in excess, corresponds to:

\% excess =(1-\frac{113.42mol}{151.58mol})*100\%\\ \\\%excess=25.2\%

Regards.

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