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olga_2 [115]
3 years ago
10

Be sure to answer all parts. In the average adult male, the residual volume (RV) of the lungs, the volume of air remaining after

a forced exhalation, is 1,200. mL.
(a) How many moles of air are present in the RV at 1.00 atm and 37.0°C? mol air
(b) How many molecules of gas are present under these conditions? × 10 molecules air
Chemistry
1 answer:
Alenkinab [10]3 years ago
7 0

<u>Answer:</u>

<u>For a:</u> The number of moles of air present in the RV is 0.047 moles

<u>For b:</u> The number of molecules of gas is 2.83\times 10^{22}

<u>Explanation:</u>

  • <u>For a:</u>

To calculate the number of moles, we use the equation given by ideal gas follows:

PV=nRT

where,

P = pressure of the air = 1.00 atm

V = Volume of the air = 1200 mL = 1.2 L    (Conversion factor:  1 L = 1000 mL)

T = Temperature of the air = 37^oC=[37+273]K=310K

R = Gas constant = 0.0821\text{ L. atm }mol^{-1}K^{-1}

n = number of moles of air = ?

Putting values in above equation, we get:

1.00atm\times 1.2L=n_{air}\times 0.0821\text{ L atm }mol^{-1}K^{-1}\times 310K\\n_{air}=\frac{1.00\times 1.2}{0.0821\times 310}=0.047mol

Hence, the number of moles of air present in the RV is 0.047 moles

  • <u>For b:</u>

According to mole concept:

1 mole of a compound contains 6.022\times 10^{23} number of molecules.

So, 0.047 moles of air will contain (0.047\times 6.022\times 10^{23})=2.83\times 10^{22} number of gas molecules.

Hence, the number of molecules of gas is 2.83\times 10^{22}

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Answer:

a) The rate law is: v = k[NO]² [O₂]

b) The units are: M⁻² s⁻¹

c) The average value of the constant is: 7.11 x 10³ M⁻² s⁻¹

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e) The rate of disappearance of O₂ is 0.4 M/s

Explanation:

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v3 = k ([NO]₃)ᵃ ([O₂]₃)ᵇ = 1.13 x 10⁻¹ M/s

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k = rate constant

[NO]₁ = concentration of NO in experiment 1

[NO]₂ = concentration of NO in experiment 2

[NO]₃ = concentration of NO in experiment 3

[O₂]₁ = concentration of O₂ in experiment 1

[O₂]₂ = concentration of O₂ in experiment 2

[O₂]₃ = concentration of O₂ in experiment 3

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[NO]₂ = 2[NO]₁

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So, v2 can be written in terms of the concentrations used in experiment 1 replacing [NO]₂ for 2[NO]₁ and [O₂]₂ by [O₂]₁ :

v2 = k (2 [NO]₁)ᵃ ([O₂]₁)ᵇ

If we rationalize v2/v1, we will have:

v2/v1 = k *2ᵃ * ([NO]₁)ᵃ * ([O₂]₁)ᵇ / k * ([NO]₁)ᵃ * ([O₂]₁)ᵇ (the exponent "a" has been distributed)

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In the same way, we can find b using the data from experiment 2 and 3 and writting v3 in terms of the concentrations used in experiment 2:

v3/v2 = k ([NO]₂)² * 2ᵇ * ([O₂]₁)ᵇ / k * ([NO]₂)² * ([O₂]₂)ᵇ

v3/v2 = 2ᵇ

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b = 1

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<u>v = k[NO]² [O₂]</u>

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M/s = k * M³

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for experiment 2:

k = 7.11 x 10³ M⁻² s⁻¹

for experiment 3:

k = 7.12 x 10³ M⁻² s⁻¹

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With calculations:

v = Δ [O₂] / Δt = 0.4 M/s (since the stoichiometric coefficient is 1, the rate of disappearance of O₂ equals the rate of the reaction).

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