Question

Calculate the standard potential for the following galvanic cell: Fe(s) | Fe2+(aq) || Ag+(aq) | Ag(s) which has the overall balanced equation: Fe(s)+2Ag+(aq)→Fe2+(aq)+2Ag(s) Express your answer to three significant figures and include the appropriate units. View Available Hint(s)

Answer 1

Answer:

E° = 1.24 V

Explanation:

Let's consider the following galvanic cell: Fe(s) | Fe²⁺(aq) || Ag⁺(aq) | Ag(s)

According to this notation, Fe is in the anode (where oxidation occurs) and Ag is in the cathode (where reduction occurs). The corresponding half-reactions are:

Anode: Fe(s) ⇒ Fe²⁺(aq) + 2 e⁻

Cathode: Ag⁺(aq) + 1 e⁻ ⇒ Ag(s)

The standard cell potential (E°) is the difference between the standard reduction potential of the cathode and the standard reduction potential of the anode.

E° = E°red, cat - E°red, an

E° = 0.80 V - (-0.44 V) = 1.24 V