Answer:
1.
Since both components of these solutions have the same molar mass, mole fractions would be the same as mass fractions.
0.110 atm = (2/3)(Pi) + (1/3)(Pn) [1]
0.089 atm = (1/3)(Pi) + (2/3)(Pn) [2]
2*[1] - [2]:
(2)(0.110) - 0.089 atm = Pi
Pi = 0.131 atm
2*[2] - [1]:
(2)(0.089) - 0.110 atm = Pn
Pn = 0.068 atm
2.
The hydroxyl (-OH) group on the end of a longer 1-propanol molecule makes it more polar than IPA. It follows that the intermolecular forces between 1-propanol are stronger than those of IPA and thus the vapor pressure of 1-propanol should be lower than IPA.
Explanation:
