Answer:
a. True
b. False
c. True
d. False
e. False
Explanation:
A. (true) The equilibrium constant K is defined as
In any case
aA +Bb ⇌ Cd +dD
where K is:
![K= \frac{[C]^{c}[D]^{d}}{[A]^{a}[B]^{b}}](https://tex.z-dn.net/?f=K%3D%20%5Cfrac%7B%5BC%5D%5E%7Bc%7D%5BD%5D%5E%7Bd%7D%7D%7B%5BA%5D%5E%7Ba%7D%5BB%5D%5E%7Bb%7D%7D)
A large value on K means that the concentration of products is bigger than the concentrations of reagents, so the forward reaction is favored, and the equilibrium lies to the right.
B. (False) When we work with gases, we use partial pressure to make calculations in the equilibrium, so we estimate Kp as:

Using the ideal gas law, we can get a relationship between K and Kp
Pv=nRT where
we know that
is the molar concentration. When we replace P in the expression for Kp we get:
![Kp= \frac{[C]^{c}*(RT)^{c}[D]^{d}*(RT)^{d}}{[A]^{a}*(RT)^{a}[B]^{b}*(RT)^{b}}](https://tex.z-dn.net/?f=Kp%3D%20%5Cfrac%7B%5BC%5D%5E%7Bc%7D%2A%28RT%29%5E%7Bc%7D%5BD%5D%5E%7Bd%7D%2A%28RT%29%5E%7Bd%7D%7D%7B%5BA%5D%5E%7Ba%7D%2A%28RT%29%5E%7Ba%7D%5BB%5D%5E%7Bb%7D%2A%28RT%29%5E%7Bb%7D%7D)
Reorganizing the equation:
![Kp= \frac{[C]^{c}[D]^{d}}{[A]^{a}[B]^{b}}*\frac{(RT)^{c+d}}{(RT)^{a+b}}](https://tex.z-dn.net/?f=Kp%3D%20%5Cfrac%7B%5BC%5D%5E%7Bc%7D%5BD%5D%5E%7Bd%7D%7D%7B%5BA%5D%5E%7Ba%7D%5BB%5D%5E%7Bb%7D%7D%2A%5Cfrac%7B%28RT%29%5E%7Bc%2Bd%7D%7D%7B%28RT%29%5E%7Ba%2Bb%7D%7D)
We can see K in the expression
Delta n = c+d-a-b
For the reaction

Delta n = 2-1-1=0
So Kp=K in this case.
C. (true) The value of K just depends on the temperature that’s why changing the among of products won’t have any effect on its value.
D. (false) as we can see this reaction involve a heterogeneous system with solids and gases. For convention the concentration for solids and liquids can be considered constant during the reaction that’s why they’re not include in the calculation for the equilibrium constant. Taking this into account the expression for the equilibrium for this reaction is:
So we can see that
is not include in the expression.
E. (False) The equilibrium is defined as the point where the rate of the forward reaction is the same to the rate of the reverse reaction. The value of K is telling you which reaction is favored but the rate of both reactions is the same in this point. (see picture)
In the area of positive charge, neutral body gets negative charge for making a dipole whereas when negative charge bought near neutral one, it gets positive charge for the same reason.........making polarization
Answer:
The theoretical yield of
Li
3
N
is
20.9 g
.
Explanation:
Balanced Equation
6Li(s)
+
N
2
(
g
)
→
2Li
3
N(s)
In order to determine the theoretical yield, we must first find the limiting reactant (reagent), which will determine the greatest possible amount of product that can be produced.
Molar Masses
Li
:
6.941 g/mol
N
2
:
(
2
×
14.007
g/mol
)
=
28.014 g/mol
Li
3
N
:
(
3
×
6.941
g/mol Li
)
+
(
1
×
14.007
g/mol N
)
=
34.83 g/mol Li
3
N
Limiting Reactant
Divide the mass of each reactant by its molar mass, then multiply times the mole ratio from the balanced equation with the product on top and the reactant on bottom, then multiply times the molar mass of
Li
3
N
.
Lithium
12.5
g Li
×
1
mol Li
6.941
g Li
×
2
mol Li
3
N
6
mol Li
×
34.83
g Li
3
N
1
mol Li
3
N
=
20.9 g Li
3
N
Nitrogen Gas
34.1
g N
2
×
1
mol N
2
28.014
g N
2
×
2
mol Li
3
N
1
mol N
2
×
34.83
g Li
3
N
1
mol Li
3
N
=
84.8 g Li
3
N
Lithium produces less lithium nitride than nitrogen gas. Therefore, the limiting reactant is lithium, and the theoretical yield of lithium nitride is
20.9 g
.
Explanation:
Answer: 4 mol
C + 2S = CS2
1 mol of CS2 contains 2 mol of sulfur
So 2 mol of cs2 contains 2*2 mol of S
2mol CS2 x 2 mol S/ 1 mol CS2 =
4 mol S