Answer:
Explanation:
Given the details, we can say that
Pure methanol is a volatile solvent as the vapour pressure has a high value. This means that methanol - methanol intermolecular forces are weak in comparisson to water - water forces. When having about 30% of water in a methanol mixture, the mixture Pv decreased, showing that it is not a volatile mixture, so then there are strong intermolecular interactions between methanol - water, part of it due to the hydrogen bonds.
A. Iron D. Nickel hope this helps you!
The question is missing the molecules in which the integration ratio of 2:3 will be observed. The complete question is given in the attachment.
Answer:
Molecule (a), (c), and (f) will show two peaks with the integration ratio of 2:3 in their 1H NMR spectrum
Explanation:
In the 1H NMR spectrum, the peak area is dependent on the number of hydrogen in a specific chemical environment. Hence, the ratio of the integration of these signals provides us with the relative number of hydrogen in two peaks. This rationale is used for the assignment of molecules that will give 2:3 integration ratio in the given problem.
- Molecule (a) have two CH₂ and three CH₃ groups. Hence, it will give two peaks and their integration ratio becomes 2:3 (Answer)
- Molecule (b) contains three chemical environments for its hydrogen atoms
- Molecule (c) have a single CH₂ and CH₃ group giving integration ratio of 2:3 (Answer)
- Molecule (d) will give two peaks but their ratio will be 1:3 because of two hydrogens of CH₂ and six hydrogens from two CH₃ groups
- Molecule (e) have three CH and three CH₃ groups, so their ratio will become 1:3
- Molecule (f) contains four CH and two CH₃ groups, giving two peaks. So, the integration ratio of their peaks is 2:3 (Answer)
- Molecules
- (g)
- and
- (h)
- both have two CH and two CH₃ groups giving two peaks with the integration ratio of 1:3
1000 to the power 4 not so good at math but